Optically active transition-metal complexes. CIV: Asymmetric Michael reactions on (RFe)- and (SFe)-[(η5-C5H5)Fe(CO)(PPh3)COCH=CH2]. Synthesis of an enantiomerically pure precursor for verapamil. X-ray crystal structure of (RFeRC)-{(η5-C5H5)Fe(Co)(PPh3)COCH2CH2C(CN)(iPr)-[3,4-C6H3(OMe)2]}
- Author
- BRUNNER, H1 ; FORSTER, S1 ; NUBER, B
[1] Univ. Regensburg, Inst. Anorganische Chemie, 93040 Regensburg, Germany - Source
Organometallics. 1993, Vol 12, Num 10, pp 3819-3827 ; ref : 27 ref
- CODEN
- ORGND7
- ISSN
- 0276-7333
- Scientific domain
- Inorganic chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Acide carboxylique Activité optique Addition Michaël Complexe acyl Complexe dinucléaire Complexe hapto Complexe mu Complexe trinucléaire Composé benzénique Configuration absolue Coordinat organique Diacide carboxylique Diéther Démétallation Fer Carbonyle Complexe Fer Composé organique Lithiation Nitrile Phosphine tertiaire Réaction asymétrique Butyronitrile(2-[3,4-diméthoxyphényl]-3-méthyl) Capronitrile(4,6-diformyl-2-[3,4-diméthoxyphényl]-2-isopropyl) Caproïque acide(4-cyano-4-[3,4-diméthoxyphényl]-5-méthyl) Diffraction RX Etude expérimentale Fer(4-cyano-4-[3,4-diméthoxyphényl]-5-méthylhexanoyl η5-cyclopentadiényl) complexe Fer(acryloyl η5-cyclopentadiényl) complexe Glutarique acide(2-[2-cyano-2-(3,4-diméthoxyphényl)-3-méthylbutyl]) Structure cristalline Structure moléculaire Triphénylphosphine Métal transition Carbonyle Complexe
- Keyword (en)
- Carboxylic acid Optical activity Michael addition Acyl complex Dinuclear complex Hapto complex Mu complex Trinuclear complex Benzenic compound Absolute configuration Organic ligand Dicarboxylic acid Diether Demetallation Iron Carbonyl Complexes Iron Organic compounds Lithiation Nitrile Tertiary phosphine Asymmetric reaction Transition metal Carbonyl Complexes
- Keyword (es)
- Acido carboxílico Actividad óptica Adición Michael Complejo acil Complejo dinuclear Complejo hapto Complejo mu Complejo trinuclear Compuesto bencénico Configuración absoluta Ligando orgánico Diácido carboxílico Dieter Desmetalación Hierro Carbonilo Complejo Hierro Compuesto orgánico Litiación Nitrilo Fosfina terciaria Reacción asimétrica Metal transición Carbonilo Complejo
- Classification
- Pascal
- 001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66H Organic compounds / 001B60A66H1 Organometalloidal and organometallic compounds
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C01 Organometalloidal and organometallic compounds / 001C03C01H Transition metals derivatives
- Discipline
- Organic chemistry Physics of condensed state : structure, mechanical and thermal properties
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 3765111
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/om00034a013 
https://dx.doi.org/10.1021/om00034a013
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