Synthesis of polycyclic cyclobutane derivatives by tandom intramolecular Michael-Aldol reaction under two complementary conditions : TBDMSOTf-Et3N and TMSI-(TSM)2NH
- Author
- IHARA, M1 ; TANIGUCHI, T1 ; MAKITA, K1 ; TAKANO, M1 ; OHNISHI, M1 ; TANIGUCHI, N1 ; FUKUMOTO, K1 ; KABUTO, C
[1] Tohoku univ., pharmaceutical inst., Aobayama, Sendai 980, Japan - Source
Journal of the American Chemical Society. 1993, Vol 115, Num 18, pp 8107-8115 ; ref : 22 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Addition Michaël Alcool primaire Alcool tertiaire Aldolisation Composé aliphatique Composé bicyclique Composé monocyclique Composé saturé Composé tricyclique Composé tétracyclique Composé vinylique Cétone Diol Réaction intramoléculaire Réaction tandem Stéréosélectivité Bicyclo[3.2.1]octane-6-acétique acide(4-oxo) ester méthyle Cyclobuta[cd]pentalène dérivé Cyclopenta[1,4]cyclobuta[1,2-a]cyclopropa[c]cyclopentène dérivé Cyclopenta[1,4]cyclobuta[1,2]benzène dérivé Hex-2-énoïque acide(6-[2-oxobicyclo[3.1.0]hex-3-yl]) ester méthyle Hex-2-énoïque acide(6-[2-oxocyclohexyl]) ester méthyle Isocrotonique acide(4-[4-oxocyclohexyl]) ester méthyle Méthanesulfonique acide(trifluoro) ester t-butyldiméthylsilyle Pent-2-énoïque acide(5-[3,3-diméthyl-3-oxocyclopentyl]) ester méthyle Tricyclo[4.2.1.03,8]nonane dérivé Triéthylamine
- Keyword (en)
- Michael addition Primary alcohol Tertiary alcohol Aldol condensation Aliphatic compound Bicyclic compound Monocyclic compound Saturated compound Tricyclic compound Tetracyclic compound Vinylic compound Ketone Diol Intramolecular reaction Tandem reaction Stereoselectivity
- Keyword (es)
- Adición Michael Alcohol primario Alcohol terciario Aldolización Compuesto alifático Compuesto bicíclico Compuesto monocíclico Compuesto saturado Compuesto tricíclico Compuesto tetracíclico Compuesto vinílico Cetona Diol Reacción intramolecular Reacción tándem Estereoselectividad
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05A Alicyclic compounds
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 3775486
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja00071a024 
https://dx.doi.org/10.1021/ja00071a024
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