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Ortho-metalated pyridine derivatives of the unsaturated anion [Re3(μ-H)4(CO)10]-. Syntheses and X-ray crystal structures of the tetraethylammonium salts of the anions [Re3(μ-H)3(μ-η2-NC5H4)(CO)10]- and [Re3(μ-η2-NC5H4)(CO)9(NC5H5)-

Author
BERINGHELLI, T1 ; D'ALFONSO, G1 ; CIANI, G; PROSERPIO, D. M; SIRONI, A
[1] CNR, metallorganica analito cent., dip. chimica inorganica, 20133 Milano, Italy
Source

Organometallics. 1993, Vol 12, Num 12, pp 4863-4870 ; ref : 21 ref

CODEN
ORGND7
ISSN
0276-7333
Scientific domain
Inorganic chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Complexe anionique Complexe hapto Complexe hydruro Complexe mu Complexe trinucléaire Comportement fluxionnel Coordinat organique Cycle 6 chaînons Diffraction RX Etude expérimentale Hétérocycle azote Liaison métal métal Pyridine Rhénium Carbonyle Complexe Spectre RMN Structure cristalline Structure moléculaire Température Ammonium(tétraéthyl) Hydrogène 1 Rhénium(2-pyridyl) complexe Métal transition Carbonyle Complexe Rhénium Composé organique
Keyword (en)
Anionic complex Hapto complex Hydrido complex Mu complex Trinuclear complex Fluxional behavior Organic ligand Six membered ring X ray diffraction Experimental study Nitrogen heterocycle Metal metal bond Pyridine Rhenium Carbonyl Complexes NMR spectrum Crystalline structure Molecular structure Temperature Transition metal Carbonyl Complexes Rhenium Organic compounds
Keyword (es)
Complejo aniónico Complejo hapto Complejo hidruro Complejo mu Complejo trinuclear Comportamiento variable Ligando orgánico Ciclo 6 eslabones Difracción RX Estudio experimental Heterociclo nitrógeno Enlace metal metal Piridina Renio Carbonilo Complejo Espectro de RMN Estructura cristalina Estructura molecular Temperatura Metal transición Carbonilo Complejo Renio Compuesto orgánico
Classification
Pascal
001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66H Organic compounds / 001B60A66H1 Organometalloidal and organometallic compounds

Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C01 Organometalloidal and organometallic compounds / 001C03C01H Transition metals derivatives

Pacs
6166H Organic compounds

Discipline
Organic chemistry Physics of condensed state : structure, mechanical and thermal properties
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
3825839

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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