Synthesis of C25- and C26-steroid carboxylic acids from C22-steroids using nickelacycles as propionic and butyric acid equivalents
- Author
- FISCHER, R1 ; SCHÖNECKER, B; WALTHER, D1
[1] Freidrich Schiller univ. Jena, inst. inorganic analytical chemistry, 07743 Jena, Germany - Source
Synthesis (Stuttgart). 1993, Num 12, pp 1267-1270 ; ref : 30 ref
- CODEN
- SYNTBF
- ISSN
- 0039-7881
- Scientific domain
- Organic chemistry
- Publisher
- Thieme, New York, NY
/
Thieme, Stuttgart
- Publication country
- Germany
- Document type
- Article
- Language
- English
- Keyword (fr)
- Alcool tertiaire Alkylation Composé diénique Coordinat bidenté Coordinat organique Cycle 6 chaînons Ether Hétérocycle azote Métallocycle Nickel Complexe Réactif Grignard Stéroïde 1-Oxa-2-nickelacyclopentan-5-one complexe 2,2p-Bipyridyle Chola-1,5-diène-24-carboxylique acide(3β-t-butyldiméthylsiloxy) ester méthyle Cholesta-1,5-dién-25-ol(3β-t-butyldiméthylsiloxy) Magnésium(méthyl) iodure Prégna-1,5-diène(3β-t-butyldiméthylsiloxy-20-iodométhyl) Urée(1-méthyl-1-nitroso) Iode Composé organique Métal transition Complexe Nickel Composé organique
- Keyword (en)
- Tertiary alcohol Alkylation Dienic compound Bidentate ligand Organic ligand Six membered ring Ether Nitrogen heterocycle Metallocycle Nickel Complexes Grignard reagent Steroid Iodine Organic compounds Transition metal Complexes Nickel Organic compounds
- Keyword (es)
- Alcohol terciario Alquilación Compuesto diénico Ligando bidentado Ligando orgánico Ciclo 6 eslabones Eter Heterociclo nitrógeno Metalociclo Niquel Complejo Reactivo Grignard Esteroide Iodo Compuesto orgánico Metal transición Complejo Niquel Compuesto orgánico
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05D Steroids
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 3841379
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1055/s-1993-26040 
https://dx.doi.org/10.1055/s-1993-26040
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