Synthesis and characterization of (η5-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene
- Author
- ANTONELLI, D. M; SCHAEFER, W. P; PARKIN, G; BERCAW, J. E
California inst. technology, Arnold & Mabel Beckman Laboratories of Chemistry, Pasadena CA 91125, United States - Source
Journal of organometallic chemistry. 1993, Vol 462, Num 1-2, pp 213-220 ; ref : 29 ref
- CODEN
- JORCAI
- ISSN
- 0022-328X
- Scientific domain
- Organic chemistry; Crystallography
- Publisher
- Elsevier Science, Lausanne
- Publication country
- Switzerland
- Document type
- Article
- Language
- English
- Keyword (fr)
- Carbone monoxyde Carbène Complexe chloro Complexe hydruro Complexe imido Complexe oxo Complexe ylidène Coordinat organique Diffraction RX Ether Ethylène Etude expérimentale Furane(tétrahydro) Métallocène Réactif Grignard Réactivité chimique Sodium Hydroxyde Structure cristalline Structure moléculaire Tantale Carbonyle Complexe Benzène(azido) Complexe phénylimino Lithium borate(1-)(hydro triéthyl) Lithium(méthyl) Magnésium(éthyl) bromure Tantale(di-η5-pentaméthylcyclopentadiényl méthylène) complexe Tantale(di-η5-pentaméthylcyclopentadiényl) complexe Tantale(η5-pentaméthylcyclopentadiényl η5:η1-pentaméthylcyclopentadiénylméthyl) complexe Métal transition Carbonyle Complexe Métal transition Complexe Tantale Composé organique
- Keyword (en)
- Carbon monoxide Carbene Chloro complex Hydrido complex Imido complex Oxo complex Ylidene complex Organic ligand X ray diffraction Ether Ethylene Experimental study Tetrahydrofurane Metallocene Grignard reagent Chemical reactivity Sodium Hydroxides Crystalline structure Molecular structure Tantalum Carbonyl Complexes Transition metal Carbonyl Complexes Transition metal Complexes Tantalum Organic compounds
- Keyword (es)
- Carbono monóxido Carbeno Complejo cloro Complejo hidruro Complejo imido Complejo oxo Complejo ilideno Ligando orgánico Difracción RX Eter Etileno Estudio experimental Metaloceno Reactivo Grignard Reactividad química Sodio Hidróxido Estructura cristalina Estructura molecular Tantalio Carbonilo Complejo Metal transición Carbonilo Complejo Metal transición Complejo Tantalio Compuesto orgánico
- Classification
- Pascal
- 001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66H Organic compounds / 001B60A66H1 Organometalloidal and organometallic compounds
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C01 Organometalloidal and organometallic compounds / 001C03C01H Transition metals derivatives
- Discipline
- Organic chemistry Physics of condensed state : structure, mechanical and thermal properties
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 3849911
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
Access to the document
Install on your browser
DOI
10.1016/0022-328X(93)83360-8 
https://dx.doi.org/10.1016/0022-328X(93)83360-8
"O:13:\"PanistOpenUrl\":36:{s:10:\"\u0000*\u0000openUrl\";N;s:6:\"\u0000*\u0000idc\";N;s:6:\"\u0000*\u0000fmt\";s:7:\"journal\";s:6:\"\u0000*\u0000doi\";s:28:\"10.1016\/0022-328X(93)83360-8\";s:6:\"\u0000*\u0000pii\";s:0:\"\";s:7:\"\u0000*\u0000pmid\";s:0:\"\";s:9:\"\u0000*\u0000atitle\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:9:\"\u0000*\u0000jtitle\";s:35:\"Journal of organometallic chemistry\";s:9:\"\u0000*\u0000stitle\";s:18:\"J. organomet. chem\";s:7:\"\u0000*\u0000date\";s:4:\"1993\";s:9:\"\u0000*\u0000volume\";s:3:\"462\";s:8:\"\u0000*\u0000issue\";s:3:\"1-2\";s:8:\"\u0000*\u0000spage\";s:3:\"213\";s:8:\"\u0000*\u0000epage\";s:3:\"220\";s:8:\"\u0000*\u0000pages\";s:0:\"\";s:7:\"\u0000*\u0000issn\";s:9:\"0022-328X\";s:8:\"\u0000*\u0000eissn\";s:0:\"\";s:9:\"\u0000*\u0000aulast\";s:9:\"ANTONELLI\";s:10:\"\u0000*\u0000aufirst\";s:4:\"D. M\";s:9:\"\u0000*\u0000auinit\";s:0:\"\";s:10:\"\u0000*\u0000auinitm\";s:0:\"\";s:5:\"\u0000*\u0000au\";a:3:{i:0;s:14:\"SCHAEFER, W. P\";i:1;s:9:\"PARKIN, G\";i:2;s:12:\"BERCAW, J. E\";}s:9:\"\u0000*\u0000aucorp\";s:0:\"\";s:7:\"\u0000*\u0000isbn\";s:0:\"\";s:8:\"\u0000*\u0000coden\";s:6:\"JORCAI\";s:8:\"\u0000*\u0000genre\";s:7:\"article\";s:7:\"\u0000*\u0000part\";s:0:\"\";s:9:\"\u0000*\u0000btitle\";s:0:\"\";s:8:\"\u0000*\u0000title\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:8:\"\u0000*\u0000place\";s:8:\"Lausanne\";s:6:\"\u0000*\u0000pub\";s:16:\"Elsevier Science\";s:10:\"\u0000*\u0000edition\";s:0:\"\";s:9:\"\u0000*\u0000tpages\";s:0:\"\";s:9:\"\u0000*\u0000series\";s:0:\"\";s:8:\"\u0000*\u0000proxy\";s:30:\"http:\/\/proxyout.inist.fr:8080\/\";s:12:\"\u0000*\u0000integrite\";b:1;}"
Panist access
"O:12:\"IstexOpenUrl\":35:{s:10:\"\u0000*\u0000openUrl\";N;s:6:\"\u0000*\u0000fmt\";s:7:\"journal\";s:6:\"\u0000*\u0000doi\";s:28:\"10.1016\/0022-328X(93)83360-8\";s:6:\"\u0000*\u0000pii\";s:0:\"\";s:7:\"\u0000*\u0000pmid\";s:0:\"\";s:9:\"\u0000*\u0000atitle\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:9:\"\u0000*\u0000jtitle\";s:35:\"Journal of organometallic chemistry\";s:9:\"\u0000*\u0000stitle\";s:18:\"J. organomet. chem\";s:7:\"\u0000*\u0000date\";s:4:\"1993\";s:9:\"\u0000*\u0000volume\";s:3:\"462\";s:8:\"\u0000*\u0000issue\";s:3:\"1-2\";s:8:\"\u0000*\u0000spage\";s:3:\"213\";s:8:\"\u0000*\u0000epage\";s:3:\"220\";s:8:\"\u0000*\u0000pages\";s:0:\"\";s:7:\"\u0000*\u0000issn\";s:9:\"0022-328X\";s:8:\"\u0000*\u0000eissn\";s:0:\"\";s:9:\"\u0000*\u0000aulast\";s:9:\"ANTONELLI\";s:10:\"\u0000*\u0000aufirst\";s:4:\"D. M\";s:9:\"\u0000*\u0000auinit\";s:0:\"\";s:10:\"\u0000*\u0000auinitm\";s:0:\"\";s:5:\"\u0000*\u0000au\";a:3:{i:0;s:14:\"SCHAEFER, W. P\";i:1;s:9:\"PARKIN, G\";i:2;s:12:\"BERCAW, J. E\";}s:9:\"\u0000*\u0000aucorp\";s:0:\"\";s:7:\"\u0000*\u0000isbn\";s:0:\"\";s:8:\"\u0000*\u0000coden\";s:6:\"JORCAI\";s:8:\"\u0000*\u0000genre\";s:7:\"article\";s:7:\"\u0000*\u0000part\";s:0:\"\";s:9:\"\u0000*\u0000btitle\";s:0:\"\";s:8:\"\u0000*\u0000title\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:8:\"\u0000*\u0000place\";s:8:\"Lausanne\";s:6:\"\u0000*\u0000pub\";s:16:\"Elsevier Science\";s:10:\"\u0000*\u0000edition\";s:0:\"\";s:9:\"\u0000*\u0000tpages\";s:0:\"\";s:9:\"\u0000*\u0000series\";s:0:\"\";s:8:\"\u0000*\u0000proxy\";s:30:\"http:\/\/proxyout.inist.fr:8080\/\";s:12:\"\u0000*\u0000integrite\";b:1;}"
Istex access
"O:16:\"UnpaywallOpenUrl\":35:{s:8:\"\u0000*\u0000email\";s:27:\"assistance-portail@inist.fr\";s:6:\"\u0000*\u0000fmt\";N;s:6:\"\u0000*\u0000doi\";s:28:\"10.1016\/0022-328X(93)83360-8\";s:6:\"\u0000*\u0000pii\";N;s:7:\"\u0000*\u0000pmid\";N;s:9:\"\u0000*\u0000atitle\";N;s:9:\"\u0000*\u0000jtitle\";N;s:9:\"\u0000*\u0000stitle\";N;s:7:\"\u0000*\u0000date\";N;s:9:\"\u0000*\u0000volume\";N;s:8:\"\u0000*\u0000issue\";N;s:8:\"\u0000*\u0000spage\";N;s:8:\"\u0000*\u0000epage\";N;s:8:\"\u0000*\u0000pages\";N;s:7:\"\u0000*\u0000issn\";N;s:8:\"\u0000*\u0000eissn\";N;s:9:\"\u0000*\u0000aulast\";N;s:10:\"\u0000*\u0000aufirst\";N;s:9:\"\u0000*\u0000auinit\";N;s:10:\"\u0000*\u0000auinitm\";N;s:5:\"\u0000*\u0000au\";N;s:9:\"\u0000*\u0000aucorp\";N;s:7:\"\u0000*\u0000isbn\";N;s:8:\"\u0000*\u0000coden\";N;s:8:\"\u0000*\u0000genre\";N;s:7:\"\u0000*\u0000part\";N;s:9:\"\u0000*\u0000btitle\";N;s:8:\"\u0000*\u0000title\";N;s:8:\"\u0000*\u0000place\";N;s:6:\"\u0000*\u0000pub\";N;s:10:\"\u0000*\u0000edition\";N;s:9:\"\u0000*\u0000tpages\";N;s:9:\"\u0000*\u0000series\";N;s:8:\"\u0000*\u0000proxy\";s:30:\"http:\/\/proxyout.inist.fr:8080\/\";s:12:\"\u0000*\u0000integrite\";N;}"
Unpaywall access
"O:16:\"EuropePMCOpenUrl\":35:{s:10:\"\u0000*\u0000openUrl\";N;s:6:\"\u0000*\u0000fmt\";s:7:\"journal\";s:6:\"\u0000*\u0000doi\";s:28:\"10.1016\/0022-328X(93)83360-8\";s:6:\"\u0000*\u0000pii\";s:0:\"\";s:7:\"\u0000*\u0000pmid\";s:0:\"\";s:9:\"\u0000*\u0000atitle\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:9:\"\u0000*\u0000jtitle\";s:35:\"Journal of organometallic chemistry\";s:9:\"\u0000*\u0000stitle\";s:18:\"J. organomet. chem\";s:7:\"\u0000*\u0000date\";s:4:\"1993\";s:9:\"\u0000*\u0000volume\";s:3:\"462\";s:8:\"\u0000*\u0000issue\";s:3:\"1-2\";s:8:\"\u0000*\u0000spage\";s:3:\"213\";s:8:\"\u0000*\u0000epage\";s:3:\"220\";s:8:\"\u0000*\u0000pages\";s:0:\"\";s:7:\"\u0000*\u0000issn\";s:9:\"0022-328X\";s:8:\"\u0000*\u0000eissn\";s:0:\"\";s:9:\"\u0000*\u0000aulast\";s:9:\"ANTONELLI\";s:10:\"\u0000*\u0000aufirst\";s:4:\"D. M\";s:9:\"\u0000*\u0000auinit\";s:0:\"\";s:10:\"\u0000*\u0000auinitm\";s:0:\"\";s:5:\"\u0000*\u0000au\";a:3:{i:0;s:14:\"SCHAEFER, W. P\";i:1;s:9:\"PARKIN, G\";i:2;s:12:\"BERCAW, J. E\";}s:9:\"\u0000*\u0000aucorp\";s:0:\"\";s:7:\"\u0000*\u0000isbn\";s:0:\"\";s:8:\"\u0000*\u0000coden\";s:6:\"JORCAI\";s:8:\"\u0000*\u0000genre\";s:7:\"article\";s:7:\"\u0000*\u0000part\";s:0:\"\";s:9:\"\u0000*\u0000btitle\";s:0:\"\";s:8:\"\u0000*\u0000title\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:8:\"\u0000*\u0000place\";s:8:\"Lausanne\";s:6:\"\u0000*\u0000pub\";s:16:\"Elsevier Science\";s:10:\"\u0000*\u0000edition\";s:0:\"\";s:9:\"\u0000*\u0000tpages\";s:0:\"\";s:9:\"\u0000*\u0000series\";s:0:\"\";s:8:\"\u0000*\u0000proxy\";s:30:\"http:\/\/proxyout.inist.fr:8080\/\";s:12:\"\u0000*\u0000integrite\";b:1;}"
Europe PubMed Central access
"O:11:\"BaseOpenUrl\":35:{s:10:\"\u0000*\u0000openUrl\";N;s:6:\"\u0000*\u0000fmt\";s:7:\"journal\";s:6:\"\u0000*\u0000doi\";s:28:\"10.1016\/0022-328X(93)83360-8\";s:6:\"\u0000*\u0000pii\";s:0:\"\";s:7:\"\u0000*\u0000pmid\";s:0:\"\";s:9:\"\u0000*\u0000atitle\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:9:\"\u0000*\u0000jtitle\";s:35:\"Journal of organometallic chemistry\";s:9:\"\u0000*\u0000stitle\";s:18:\"J. organomet. chem\";s:7:\"\u0000*\u0000date\";s:4:\"1993\";s:9:\"\u0000*\u0000volume\";s:3:\"462\";s:8:\"\u0000*\u0000issue\";s:3:\"1-2\";s:8:\"\u0000*\u0000spage\";s:3:\"213\";s:8:\"\u0000*\u0000epage\";s:3:\"220\";s:8:\"\u0000*\u0000pages\";s:0:\"\";s:7:\"\u0000*\u0000issn\";s:9:\"0022-328X\";s:8:\"\u0000*\u0000eissn\";s:0:\"\";s:9:\"\u0000*\u0000aulast\";s:9:\"ANTONELLI\";s:10:\"\u0000*\u0000aufirst\";s:4:\"D. M\";s:9:\"\u0000*\u0000auinit\";s:0:\"\";s:10:\"\u0000*\u0000auinitm\";s:0:\"\";s:5:\"\u0000*\u0000au\";a:3:{i:0;s:14:\"SCHAEFER, W. P\";i:1;s:9:\"PARKIN, G\";i:2;s:12:\"BERCAW, J. E\";}s:9:\"\u0000*\u0000aucorp\";s:0:\"\";s:7:\"\u0000*\u0000isbn\";s:0:\"\";s:8:\"\u0000*\u0000coden\";s:6:\"JORCAI\";s:8:\"\u0000*\u0000genre\";s:7:\"article\";s:7:\"\u0000*\u0000part\";s:0:\"\";s:9:\"\u0000*\u0000btitle\";s:0:\"\";s:8:\"\u0000*\u0000title\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:8:\"\u0000*\u0000place\";s:8:\"Lausanne\";s:6:\"\u0000*\u0000pub\";s:16:\"Elsevier Science\";s:10:\"\u0000*\u0000edition\";s:0:\"\";s:9:\"\u0000*\u0000tpages\";s:0:\"\";s:9:\"\u0000*\u0000series\";s:0:\"\";s:8:\"\u0000*\u0000proxy\";s:30:\"http:\/\/proxyout.inist.fr:8080\/\";s:12:\"\u0000*\u0000integrite\";b:1;}"
Base Search access
"O:12:\"ArXivOpenUrl\":35:{s:10:\"\u0000*\u0000openUrl\";N;s:6:\"\u0000*\u0000fmt\";s:7:\"journal\";s:6:\"\u0000*\u0000doi\";s:28:\"10.1016\/0022-328X(93)83360-8\";s:6:\"\u0000*\u0000pii\";s:0:\"\";s:7:\"\u0000*\u0000pmid\";s:0:\"\";s:9:\"\u0000*\u0000atitle\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:9:\"\u0000*\u0000jtitle\";s:35:\"Journal of organometallic chemistry\";s:9:\"\u0000*\u0000stitle\";s:18:\"J. organomet. chem\";s:7:\"\u0000*\u0000date\";s:4:\"1993\";s:9:\"\u0000*\u0000volume\";s:3:\"462\";s:8:\"\u0000*\u0000issue\";s:3:\"1-2\";s:8:\"\u0000*\u0000spage\";s:3:\"213\";s:8:\"\u0000*\u0000epage\";s:3:\"220\";s:8:\"\u0000*\u0000pages\";s:0:\"\";s:7:\"\u0000*\u0000issn\";s:9:\"0022-328X\";s:8:\"\u0000*\u0000eissn\";s:0:\"\";s:9:\"\u0000*\u0000aulast\";s:9:\"ANTONELLI\";s:10:\"\u0000*\u0000aufirst\";s:4:\"D. M\";s:9:\"\u0000*\u0000auinit\";s:0:\"\";s:10:\"\u0000*\u0000auinitm\";s:0:\"\";s:5:\"\u0000*\u0000au\";a:3:{i:0;s:14:\"SCHAEFER, W. P\";i:1;s:9:\"PARKIN, G\";i:2;s:12:\"BERCAW, J. E\";}s:9:\"\u0000*\u0000aucorp\";s:0:\"\";s:7:\"\u0000*\u0000isbn\";s:0:\"\";s:8:\"\u0000*\u0000coden\";s:6:\"JORCAI\";s:8:\"\u0000*\u0000genre\";s:7:\"article\";s:7:\"\u0000*\u0000part\";s:0:\"\";s:9:\"\u0000*\u0000btitle\";s:0:\"\";s:8:\"\u0000*\u0000title\";s:171:\"Synthesis and characterization of (\u03b75-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene\";s:8:\"\u0000*\u0000place\";s:8:\"Lausanne\";s:6:\"\u0000*\u0000pub\";s:16:\"Elsevier Science\";s:10:\"\u0000*\u0000edition\";s:0:\"\";s:9:\"\u0000*\u0000tpages\";s:0:\"\";s:9:\"\u0000*\u0000series\";s:0:\"\";s:8:\"\u0000*\u0000proxy\";s:30:\"http:\/\/proxyout.inist.fr:8080\/\";s:12:\"\u0000*\u0000integrite\";b:1;}"
arXiv access
