Origin of anomalous kinetic parameters in carbene 1,2-shifts by direct dynamics
- Author
- STORER, J. W; HOUK, K. N
UCLA, dep. chemistry biochemistry, Los Angeles CA 90024-1569, United States - Source
Journal of the American Chemical Society. 1993, Vol 115, Num 22, pp 10426-10427 ; ref : 22 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Carbène Constante vitesse Corrélation électronique Effet tunnel Etat transition Etude théorique Fonction polarisation Paramètre activation Paramètre cinétique Partition Moller Plesset Transposition chimique Méthylène(chloro méthyl)
- Keyword (en)
- Carbene Rate constant Electron correlation Tunnel effect Transition state Theoretical study Polarization function Activation parameter Kinetic parameter Moller Plesset partition Chemical rearrangement
- Keyword (es)
- Carbeno Constante velocidad Correlación electrónica Efecto túnel Estado transitorio Estudio teórico Función polarización Parámetro activación Parámetro cinético Partición Moller Plesset Transposición química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 3850009
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja00075a095 
https://dx.doi.org/10.1021/ja00075a095
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