Syntheses and 31P NMR studies of ruthenium(II), rhodium(I), and rhodium(III) complexes containing η5-P2C3tBu3 and η5- and η1-P3C21Bu2 ligated ring systems. Crystal structures of [Rh(η5-P2C3tBu3)(η4-COD)] (COD = 1,5-cyclooctadiene) and the novel hydrido-η1-triphosphacyclopentadienyl complex {RhH(η1-P3C2tBu2)(η5-C5Me5)PPh3]
- Author
- HITCHCOCK, P. B; MATOS, R. M; NIXON, J. F
Univ. Sussex, school chemistry molecular sci., Brighton BN1 9QJ, United Kingdom - Source
Journal of organometallic chemistry. 1993, Vol 462, Num 1-2, pp 319-329 ; ref : 42 ref
- CODEN
- JORCAI
- ISSN
- 0022-328X
- Scientific domain
- Organic chemistry; Crystallography
- Publisher
- Elsevier Science, Lausanne
- Publication country
- Switzerland
- Document type
- Article
- Language
- English
- Keyword (fr)
- Arène Benzène Complexe hapto Complexe hydruro Composé aliphatique Composé diénique Composé monocyclique Composé sandwich Coordinat organique Cycle 5 chaînons Diffraction RX Etude expérimentale Hétérocycle phosphore Métallocycle Phosphine tertiaire Rhodium I Complexe Rhodium III Complexe Ruthénium II Complexe Spectre RMN Spectrométrie 2 dimensions Structure cristalline Structure moléculaire 1,2,4-Triphosphole(2,4-di-t-butyl) 1,2,4-Triphospholure(2,4-tri-t-butyl) 1,3-Diphospholure(2,4,5-tri-t-butyl) Carbone 13 Cycloocta-1,5-diène Hexa-1,5-diène Hydrogène 1 Phosphore 31 Rhodium([2,4,5-tri-t-butyl-1,3-diphospholyl]) complexe Rhodium([3,5-di-t-butyl-1,2,4-triphospholyl]) complexe Rhodium(η5-pentaméthylcyclopentadiényl) complexe Rhuthénium([3,5-di-t-butyl-1,2,4-triphospholyl] 2-[diphénylphosphino]phényl) complexe Rhuthénium(η5-cyclooctadiényl [2,4,5-tri-t-butyl-1,3-diphospholyl]) complexe Triphénylphosphine Complexe Mixte Métal divalent Complexe Métal monovalent Complexe Métal transition Complexe Métal trivalent Complexe Phosphore Composé organique Platinoïde Complexe Rhodium Composé organique Ruthénium Composé organique
- Keyword (en)
- Arene Benzene Hapto complex Hydrido complex Aliphatic compound Dienic compound Monocyclic compound Sandwich compound Organic ligand Five membered ring X ray diffraction Experimental study Phosphorus heterocycle Metallocycle Tertiary phosphine Rhodium I Complexes Rhodium III Complexes Ruthenium II Complexes NMR spectrum Two dimension spectrometry Crystalline structure Molecular structure Complexes Mixed Divalent metal Complexes Univalent metal Complexes Transition metal Complexes Trivalent metal Complexes Phosphorus Organic compounds Platinoid Complexes Rhodium Organic compounds Ruthenium Organic compounds
- Keyword (es)
- Areno Benceno Complejo hapto Complejo hidruro Compuesto alifático Compuesto diénico Compuesto monocíclico Compuesto sandwich Ligando orgánico Ciclo 5 eslabones Difracción RX Estudio experimental Heterociclo fósforo Metalociclo Fosfina terciaria Rodio I Complejo Rodio III Complejo Rutenio II Complejo Espectro de RMN Espectrometría bidimensional Estructura cristalina Estructura molecular Complejo Mixto Metal divalente Complejo Metal monovalente Complejo Metal transición Complejo Metal trivalente Complejo Fósforo Compuesto orgánico Platinoide Complejo Rodio Compuesto orgánico Rutenio Compuesto orgánico
- Classification
- Pascal
- 001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66H Organic compounds / 001B60A66H1 Organometalloidal and organometallic compounds
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C01 Organometalloidal and organometallic compounds / 001C03C01H Transition metals derivatives
- Discipline
- Organic chemistry Physics of condensed state : structure, mechanical and thermal properties
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 3851500
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1016/0022-328X(93)83373-4 
https://dx.doi.org/10.1016/0022-328X(93)83373-4
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Base Search access
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