One-electron oxidation of 2,2-dimethyl-2-silaindane by potassium 12-tungstocobaltate(III). Lack of evidence for stereoelectronic effects on the cleavage of a β-carbon-silicon bond in an aromatic cation radical
- Author
- BACIOCCHI, E; BERNINI, R; LANZALUNGA, O
Univ. La Sapienza, dip. chimica, 00185 Roma, Italy - Source
Journal of the Chemical Society. Chemical communications. 1993, Num 22, pp 1691-1692 ; ref : 5 ref
- CODEN
- JCCCAT
- ISSN
- 0022-4936
- Scientific domain
- Chemistry; Crystallography; Atomic molecular physics
- Publisher
- Royal Society of Chemistry, Cambridge
- Publication country
- United Kingdom
- Document type
- Article
- Language
- English
- Keyword (fr)
- Composé aromatique Composé bicyclique Constante vitesse Effet électronique Etude expérimentale Hétérocycle silicium Hétéropolysel Intermédiaire réaction Oxydation Paramètre cinétique Radical libre organique cationique Transfert électron 2-Silaindane(2,2-diméthyl) Co K O W Composé quaternaire K5CoW12O40 Tungstocobaltate Potassium Composé Silicium Composé organique
- Keyword (en)
- Aromatic compound Bicyclic compound Rate constant Electronic effect Experimental study Silicon heterocycle Heteropolysalt Reaction intermediate Oxidation Kinetic parameter Organic radical cation Electron transfer Quaternary compound Potassium Compounds Silicon Organic compounds
- Keyword (es)
- Compuesto aromático Compuesto bicíclico Constante velocidad Efecto electrónico Estudio experimental Heterociclo silicio Heteropolisal Intermediario reacción Oxidación Parámetro cinético Radical libre orgánico catiónico Transferencia electrón Potasio Compuesto Silicio Compuesto orgánico
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 3899853
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1039/C39930001691 
https://dx.doi.org/10.1039/C39930001691
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