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One-electron oxidation of 2,2-dimethyl-2-silaindane by potassium 12-tungstocobaltate(III). Lack of evidence for stereoelectronic effects on the cleavage of a β-carbon-silicon bond in an aromatic cation radical

Author
BACIOCCHI, E; BERNINI, R; LANZALUNGA, O
Univ. La Sapienza, dip. chimica, 00185 Roma, Italy
Source

Journal of the Chemical Society. Chemical communications. 1993, Num 22, pp 1691-1692 ; ref : 5 ref

CODEN
JCCCAT
ISSN
0022-4936
Scientific domain
Chemistry; Crystallography; Atomic molecular physics
Publisher
Royal Society of Chemistry, Cambridge
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Composé aromatique Composé bicyclique Constante vitesse Effet électronique Etude expérimentale Hétérocycle silicium Hétéropolysel Intermédiaire réaction Oxydation Paramètre cinétique Radical libre organique cationique Transfert électron 2-Silaindane(2,2-diméthyl) Co K O W Composé quaternaire K5CoW12O40 Tungstocobaltate Potassium Composé Silicium Composé organique
Keyword (en)
Aromatic compound Bicyclic compound Rate constant Electronic effect Experimental study Silicon heterocycle Heteropolysalt Reaction intermediate Oxidation Kinetic parameter Organic radical cation Electron transfer Quaternary compound Potassium Compounds Silicon Organic compounds
Keyword (es)
Compuesto aromático Compuesto bicíclico Constante velocidad Efecto electrónico Estudio experimental Heterociclo silicio Heteropolisal Intermediario reacción Oxidación Parámetro cinético Radical libre orgánico catiónico Transferencia electrón Potasio Compuesto Silicio Compuesto orgánico
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
3899853

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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