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Organic synthesis utilizing Beckmann fragmentation : highly stereoselective C-C bond formation in the reaction of 2,3-isopropylidenedioxycyclohexanone oxime esters with organoaluminium reagents

Author
FUJIOKA, H; MIYAZAKI, M; KITAGAWA, H; YAMANAKA, T; YAMAMOTO, H; TAKUMA, K; KITA, Y
Osaka univ., fac. pharmaceutical sci., Suita, Osaka 565, Japan
Source

Journal of the Chemical Society. Chemical communications. 1993, Num 21, pp 1634-1636 ; ref : 4 ref

CODEN
JCCCAT
ISSN
0022-4936
Scientific domain
Chemistry; Crystallography; Atomic molecular physics
Publisher
Royal Society of Chemistry, Cambridge
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Acétal Composé bicyclique Cycle 5 chaînons Cétoxime Hétérocycle oxygène Nitrile Racémique Stéréosélectivité Zinc II Chlorure 1,3-Benzodioxol-4-one(2,2-diméthyl-perhydro) [2,6-dichlorobenzoyloxime] 1,3-Benzodioxol-4-one(2,2-diméthyl-perhydro) acétyloxime 1,3-Dioxolane-4-butyrique acide(2,2-diméthyl-5-éthyl) ester méthyle 1,3-Dioxolane-4-butyronitrile(2,2-diméthyl-5-éthyl) 6,8-Dioxobicyclo [3-2-1] octane dérivé Aluminium(trialkyl) Aluminium Composé organique
Keyword (en)
Acetal Bicyclic compound Five membered ring Ketoxime Oxygen heterocycle Nitrile Racemate Stereoselectivity Zinc II Chlorides Aluminium Organic compounds
Keyword (es)
Acetal Compuesto bicíclico Ciclo 5 eslabones Cetoxima Heterociclo oxígeno Nitrilo Racémico Estereoselectividad Zinc II Cloruro Aluminio Compuesto orgánico
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06A Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
3961279

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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