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Synthesis and carbohydrates via tandem use of the osmium-catalyzed asymmetric dihydroxylation and enzyme-catalyzed aldol addition reactions

Author
HENDERSON, I; SHARPLESS, K. B; CHI-HUEY WONG
Scripps res. inst., dep. chemistry, La Jolla CA 92037, United States
Source

Journal of the American Chemical Society. 1994, Vol 116, Num 2, pp 558-561

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Acétal Aldehyde-lyases Aldolisation Aldose Catalyse asymétrique Composé vinylique Coordinat organique Cétol Cétose Fructose Hydroxylation Osmium Complexe Osmium VIII Oxyde Réaction enzymatique Réaction tandem Stéréoisomère D-galacto Stéréoisomère L Stéréosélectivité 2,4-Benzodioxépine(1,5-dihydro-3-[1,2-dihydroxyéthyl]) 2,4-Benzodioxépine(1,5-dihydro-3-vinyl) Glycéraldéhyde Hept-2-ulose Hex-2-ulose Phosphate(3-hydroxyacétonyl) Stéréoisomère L-galacto Carbon-carbon lyases Enzyme Lyases Phosphore Composé organique
Keyword (en)
Acetal Aldehyde-lyases Aldol condensation Aldose Asymmetric catalysis Vinylic compound Organic ligand Ketol Ketose Fructose Hydroxylation Osmium Complexes Osmium VIII Oxides Enzymatic reaction Tandem reaction D-galacto stereoisomer L stereoisomer Stereoselectivity L-galacto stereoisomer Carbon-carbon lyases Enzyme Lyases Phosphorus Organic compounds
Keyword (es)
Acetal Aldehyde-lyases Aldolización Aldosa Catálisis asimétrica Compuesto vinílico Ligando orgánico Cetol Cetosa Fructosa Hidroxilación Osmio Complejo Osmio VIII Óxido Reacción enzimática Reacción tándem Estereoisómero D-galacto Estereoisómero L Estereoselectividad Carbon-carbon lyases Enzima Lyases Fósforo Compuesto orgánico
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C07 Carbohydrates. Nucleosides and nucleotides / 001C03C07A Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
3983332

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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