Kinetics and mechanism of the isomerization of 1H-indene-1-carboxylic acid to 1H-indene-3-carboxylic acid in aqueous solution and determination of their keto-enol equilibrium constants and acid dissociation constants of the keto and enol forms. Implications on the photolysis of diazonaphthoquinones
- Author
- ANDRAOS, J; KRESGE, A. J; POPIK, V. V
Univ. Toronto, dep. chemistry, Toronto ON M5S 1A1, Canada - Source
Journal of the American Chemical Society. 1994, Vol 116, Num 3, pp 961-967 ; ref : 22 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Acide carboxylique Composé aromatique Composé bicyclique Constante dissociation Constante vitesse Constante équilibre Equilibre chimique Etude expérimentale Isomérisation Mécanisme réaction Paramètre cinétique Propriété chimique Solution aqueuse Solution diluée Tautomérie cétoénolique Indène-1-carboxylique acide Indène-3-carboxylique acide
- Keyword (en)
- Carboxylic acid Aromatic compound Bicyclic compound Dissociation constant Rate constant Equilibrium constant Chemical equilibrium Experimental study Isomerization Reaction mechanism Kinetic parameter Chemical properties Aqueous solution Dilute solution Keto enol tautomerism
- Keyword (es)
- Acido carboxílico Compuesto aromático Compuesto bicíclico Constante disociación Constante velocidad Constante equilibrio Equilibrio químico Estudio experimental Isomerización Mecanismo reacción Parámetro cinético Propiedad química Solución acuosa Solución diluida Tautomería ceto-enólica
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 4002576
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja00082a017 
https://dx.doi.org/10.1021/ja00082a017
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