Synthesis of polyfunctionalized 1-aminobuta-1,3-dienes by addition of dimethyl acetylenedicarboxylate to (Z)-β-enamino-λ5-phosphazenes. Configurational and conformational analysis bases on NOE data, nJPX coupling constant, X-ray structures, and semiempirical calculations
- Author
- LOPEZ-ORTIZ, F1 ; PELAEZ-ARANGO, E1 ; PALACIOS, F1 ; BARLUENGA, J1 ; GARCIA-GRANDA, S; TEJERINA, B; GARCIA-FERNANDEZ, A
[1] Univ. Oviedo, dep. química orgánica inorgánica, 33071 Oviedo, Spain - Source
Journal of organic chemistry. 1994, Vol 59, Num 8, pp 1984-1992
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Addition chimique Analyse conformationnelle Composé acétylénique Composé aliphatique Composé diénique conjugué Composé organique Diester Diffraction RX Effet Overhauser Enamine Etude expérimentale Méthode semiempirique Paramètre RMN Phosphine tertiaire imine Régiosélectivité Structure cristalline Structure moléculaire Benzamide(N-[(2-aminovinyl diphényl)phosphoranylidène]) Butynedioïque acide ester diméthyle Butènedioïque acide(2-[2-amino-1-([benzoylimino diphényl]phosphoranyl)vinyl]) ester diméthyle
- Keyword (en)
- Addition reaction Conformational analysis Acetylenic compound Aliphatic compound Conjugated dienic compound Organic compounds Diester X ray diffraction Overhauser effect Enamine Experimental study Semiempirical method NMR parameter Tertiary phosphine imine Regioselectivity Crystalline structure Molecular structure
- Keyword (es)
- Adición química Análisis conformacional Compuesto acetilénico Compuesto alifático Compuesto diénico conjugado Compuesto orgánico Diester Difracción RX Efecto Overhauser Enamina Estudio experimental Método semiempírico Parámetro RMN Fosfina terciaria imina Regioselectividad Estructura cristalina Estructura molecular
- Classification
- Pascal
- 001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66H Organic compounds / 001B60A66H2 Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C02 Aliphatic compounds
- Discipline
- Organic chemistry Physics of condensed state : structure, mechanical and thermal properties
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 4038644
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo00087a010 
https://dx.doi.org/10.1021/jo00087a010
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