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Sulfone directed alkylative bridge cleavage of oxabicyclic vinyl sulfones with organolithium reagents

Author
ARJONA, O; DE DIOS, A; FERNANDEZ DE LA PRADILLA, R; PLUMET, J; VISO, A
Univ. Complutense, fac. quιmica, dep. quιmica orgánica I, 28040 Madrid, Spain
Source

Journal of organic chemistry. 1994, Vol 59, Num 14, pp 3906-3916 ; ref : 43 ref

CODEN
JOCEAH
ISSN
0022-3263
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Alkylation Composé monocyclique Composé vinylique Décyclisation Hydroxysulfone Hétérocycle oxygène Régiosélectivité Stéréosélectivité 7-Oxabicyclo[2.2.1]hept-2-ène(6-alcoxy-2-benzènesulfonyl) 8-Oxabicyclo[3.2.1]oct-2-ène(7-alcoxy-2-benzènesulfonyl) Cyclohept-3-énol(7-alcoxy-2-alkyl-3-benzènesulfonyl) Cyclohex-3-énol(5-alcoxy-2-alkyl-3-benzènesulfonyl) Lithium(alkyl)
Keyword (en)
Alkylation Monocyclic compound Vinylic compound Ring cleavage Hydroxysulfone Oxygen heterocycle Regioselectivity Stereoselectivity
Keyword (es)
Alquilación Compuesto monocíclico Compuesto vinílico Desciclización Hidroxisulfona Heterociclo oxígeno Regioselectividad Estereoselectividad
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05A Alicyclic compounds

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
4142132

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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