Oxidative addition of alkyl halides to rhodium(I) and iridium(I) dicarbonyl diiodides : key reactions in the catalytic carbonylation of alcohols
- Author
- ELLIS, P. R; PEARSON, J. M; HAYNES, A; ADAMS, H; BAILEY, N. A; MAITLIS, P. M
Univ. Sheffield, dep. chemistry, Sheffield S3 7HF, United Kingdom - Source
Organometallics. 1994, Vol 13, Num 8, pp 3215-3226
- CODEN
- ORGND7
- ISSN
- 0276-7333
- Scientific domain
- Inorganic chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Addition chimique Cinétique Complexe anionique Complexe iodo Composé aliphatique Diffraction RX Effet substituant Etude expérimentale Insertion Iridium I Carbonyle Complexe Isomérisation Mécanisme réaction Oxydation Propriété thermodynamique Rhodium I Carbonyle Complexe Structure cristalline Structure moléculaire Alcane(iodo) Arsonium(tétraphényl) Iridium(alkyl) complexe Iridium(hexyl) complexe Rhodium(acyl) complexe Iridium Composé organique Métal monovalent Complexe Métal transition Carbonyle Complexe Platinoïde Carbonyle Complexe Rhodium Composé organique
- Keyword (en)
- Addition reaction Kinetics Anionic complex Iodo complex Aliphatic compound X ray diffraction Substituent effect Experimental study Insertion Iridium I Carbonyl Complexes Isomerization Reaction mechanism Oxidation Thermodynamic properties Rhodium I Carbonyl Complexes Crystalline structure Molecular structure Iridium Organic compounds Univalent metal Complexes Transition metal Carbonyl Complexes Platinoid Carbonyl Complexes Rhodium Organic compounds
- Keyword (es)
- Adición química Cinética Complejo aniónico Complejo iodo Compuesto alifático Difracción RX Efecto sustituyente Estudio experimental Inserción Iridio I Carbonilo Complejo Isomerización Mecanismo reacción Oxidación Propiedad termodinámica Rodio I Carbonilo Complejo Estructura cristalina Estructura molecular Iridio Compuesto orgánico Metal monovalente Complejo Metal transición Carbonilo Complejo Platinoide Carbonilo Complejo Rodio Compuesto orgánico
- Classification
- Pascal
- 001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66H Organic compounds / 001B60A66H1 Organometalloidal and organometallic compounds
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C01 Organometalloidal and organometallic compounds / 001C03C01H Transition metals derivatives
- Discipline
- Organic chemistry Physics of condensed state : structure, mechanical and thermal properties
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 4176161
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/om00020a039 
https://dx.doi.org/10.1021/om00020a039
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