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Oxidative addition of alkyl halides to rhodium(I) and iridium(I) dicarbonyl diiodides : key reactions in the catalytic carbonylation of alcohols

Author
ELLIS, P. R; PEARSON, J. M; HAYNES, A; ADAMS, H; BAILEY, N. A; MAITLIS, P. M
Univ. Sheffield, dep. chemistry, Sheffield S3 7HF, United Kingdom
Source

Organometallics. 1994, Vol 13, Num 8, pp 3215-3226

CODEN
ORGND7
ISSN
0276-7333
Scientific domain
Inorganic chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Addition chimique Cinétique Complexe anionique Complexe iodo Composé aliphatique Diffraction RX Effet substituant Etude expérimentale Insertion Iridium I Carbonyle Complexe Isomérisation Mécanisme réaction Oxydation Propriété thermodynamique Rhodium I Carbonyle Complexe Structure cristalline Structure moléculaire Alcane(iodo) Arsonium(tétraphényl) Iridium(alkyl) complexe Iridium(hexyl) complexe Rhodium(acyl) complexe Iridium Composé organique Métal monovalent Complexe Métal transition Carbonyle Complexe Platinoïde Carbonyle Complexe Rhodium Composé organique
Keyword (en)
Addition reaction Kinetics Anionic complex Iodo complex Aliphatic compound X ray diffraction Substituent effect Experimental study Insertion Iridium I Carbonyl Complexes Isomerization Reaction mechanism Oxidation Thermodynamic properties Rhodium I Carbonyl Complexes Crystalline structure Molecular structure Iridium Organic compounds Univalent metal Complexes Transition metal Carbonyl Complexes Platinoid Carbonyl Complexes Rhodium Organic compounds
Keyword (es)
Adición química Cinética Complejo aniónico Complejo iodo Compuesto alifático Difracción RX Efecto sustituyente Estudio experimental Inserción Iridio I Carbonilo Complejo Isomerización Mecanismo reacción Oxidación Propiedad termodinámica Rodio I Carbonilo Complejo Estructura cristalina Estructura molecular Iridio Compuesto orgánico Metal monovalente Complejo Metal transición Carbonilo Complejo Platinoide Carbonilo Complejo Rodio Compuesto orgánico
Classification
Pascal
001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66H Organic compounds / 001B60A66H1 Organometalloidal and organometallic compounds

Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C01 Organometalloidal and organometallic compounds / 001C03C01H Transition metals derivatives

Pacs
6166H Organic compounds

Discipline
Organic chemistry Physics of condensed state : structure, mechanical and thermal properties
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
4176161

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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