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Stereochemical studies on the addition of allylsilanes to aldehydes. The SE' component

Author
DENMARK, S. E; ALMSTEAD, N. G
Univ. Illinois, dep. chemistry, Roger Adams lab., Urbana IL 61801, United States
Source

Journal of organic chemistry. 1994, Vol 59, Num 18, pp 5130-5132

CODEN
JOCEAH
ISSN
0022-3263
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Acide Lewis Aldéhyde Composé allylique Composé monocyclique Cyclisation Deutérium Hydrogène Isotope Marquage isotopique Mécanisme réaction Réaction intramoléculaire Silane organique Stéréosélectivité Substitution électrophile Acétaldéhyde(3-[([diméthyl phényl]silyl)méthyl]cyclohex-3-ényl) Bicyclo[2.2.2]octan-2-ol(6-méthylène)
Keyword (en)
Lewis acid Aldehyde Allylic compound Monocyclic compound Cyclization Deuterium Hydrogen Isotopes Isotope labelling Reaction mechanism Intramolecular reaction Organic silane Stereoselectivity Electrophilic substitution
Keyword (es)
Acido Lewis Aldehído Compuesto alílico Compuesto monocíclico Ciclización Deuterio Hidrógeno Isótopo Marcación isotópica Mecanismo reacción Reacción intramolecular Silano orgánico Estereoselectividad Sustitución electrófila
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
4219190

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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