Stereoselective epoxidations and electrophilic additions to partial ergot alkaloids and conformationally-fixed styrenes. Experimental and theoretical modeling evidence for the importance of torsional steering as a stereocontrol element
- Author
- MARTINELLI, M. J1 ; PETERSON, B. C1 ; KHAU, V. V1 ; HUTCHISON, D. R1 ; LEANNA, M. R1 ; AUDIA, J. E1 ; DROSTE, J. J1 ; YUN-DONG WU; HOUK, K. N
[1] Eli Lilly & Co., Lilly corporate cent., Lilly Research Laboratories, Indianapolis IN 46285-4813, United States - Source
Journal of organic chemistry. 1994, Vol 59, Num 8, pp 2204-2210
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Bromhydratation Composé aromatique Composé tricyclique Diastéréosélectivité Effet structure Energie totale Epoxydation Etude théorique Hydroxylation Hétérocycle azote Méthode champ force Acénaphto oxirène dérivé Acénaphtylène(1,2,2a,3-tétrahydro) Benzo[c,d]indole dérivé Oxiréno benzo indole dérivé
- Keyword (en)
- Hydrobromination Aromatic compound Tricyclic compound Diastereoselectivity Structure effect Total energy Epoxidation Theoretical study Hydroxylation Nitrogen heterocycle Force field method
- Keyword (es)
- Bromhidratación Compuesto aromático Compuesto tricíclico Diastereoselectividad Efecto estructura Energía total Epoxidación Estudio teórico Hidroxilación Heterociclo nitrógeno Método campo fuerza
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B01 Chemical reactivity
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 4245676
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo00087a042 
https://dx.doi.org/10.1021/jo00087a042
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