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(Z)-3-Methyl-3-penten-2-ol as stereochemical probe for 1,2 versus 1,3 allylic strain in the photooxygenation and epoxidation of chiral allylic alcohols

Author
ADAM, W; NESTLER, B
Univ. Würzburg, inst. organic chemistry, 8700 Würzburg, Germany
Source

Tetrahedron letters. 1993, Vol 34, Num 4, pp 611-614 ; ref : 7 ref

CODEN
TELEAY
ISSN
0040-4039
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
Elsevier, Oxford
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Alcool secondaire Composé aliphatique Composé allylique Composé chiral Effet structure Effet substituant Epoxydation Hydroperoxydation Réaction ène Réactivité chimique Stéréosélectivité Oxirane(2,3-diméthyl-2-[1-hydroxyéthyl]) Pen-3-èn-2-ol(3-méthyl) Pent-4-èn-2-ol(3-hydroperoxy-3-méthyl)
Keyword (en)
Secondary alcohol Aliphatic compound Allylic compound Chiral compound Structure effect Substituent effect Epoxidation Hydroperoxidation Ene reaction Chemical reactivity Stereoselectivity
Keyword (es)
Alcohol secundario Compuesto alifático Compuesto alílico Compuesto quiral Efecto estructura Efecto sustituyente Epoxidación Hidroperoxidación Reacción ene Reactividad química Estereoselectividad
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C02 Aliphatic compounds

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
4566747

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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