An analysis of the methyl rotation dynamics in the S0 (X 1A1) and T1 (a3A2) states of thiocetone, (CH3)2 CS and (CD3)2 CS from pyrolysis jet spectra
- Author
- MOULE, D. C1 ; SMEYERS, Y. G; SENENT, M. L; CLOUTHIER, D. J; KAROLCZAK, J; JUDGE, R. H
[1] Brock univ., dep. chemistry, Sainte Catharines ON L2S 3A1, Canada - Source
The Journal of chemical physics. 1991, Vol 95, Num 5, pp 3137-3146 ; ref : 26 ref
- CODEN
- JCPSA6
- ISSN
- 0021-9606
- Scientific domain
- Atomic molecular physics; Condensed state physics; Polymers, paint and wood industries
- Publisher
- American Institute of Physics, Woodbury, NY
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Composé aliphatique Composé organique Conformation Energie totale Espèce isotopique Etude expérimentale Etude théorique Faisceau supersonique Fonction polarisation Mode torsion Mode vibration Méthode ab initio Orbitale gaussienne Rotation interne Spectre excitation Spectre fluorescence Sulfoxyde Surface potentiel Transition vibronique Méthyle sulfoxyde
- Keyword (en)
- Aliphatic compound Organic compounds Conformation Total energy Isotopic species Experimental study Theoretical study Supersonic beam Polarization function Torsion mode Vibrational mode Ab initio method Gaussian orbital Internal rotation Excitation spectrum Fluorescence spectrum Sulfoxide Potential surface Vibronic transition
- Keyword (es)
- Compuesto alifático Compuesto orgánico Conformación Energía total Especie isotópica Estudio experimental Estudio teórico Haz supersónico Función polarización Modo torsión Modo de vibración Método ab initio Orbital gaussiano Rotación interna Espectro excitación Espectro fluorescencia Sulfóxido Superficie potencial Transición vibrónica
- Classification
- Discipline
- Atomic and molecular physics
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 4987809
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1063/1.460871 
https://dx.doi.org/10.1063/1.460871
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