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Photochemical behavior of thioxophosphoranyl diazo compounds : evidence for transcient λ5-phosphathiirenes and for structural isomerizations of the diazo group

Author
SOLEILHAVOUP, M; BACEIREDO, A; DAHAN, F; BERTRAND, G
CNRS, lab. chimie coordination, 31077 Toulouse, France
Source

Inorganic chemistry (Print). 1992, Vol 31, Num 8, pp 1500-1504 ; ref : 21 ref

CODEN
INOCAJ
ISSN
0020-1669
Scientific domain
Inorganic chemistry; Crystallography; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Composé organique Cycle 5 chaînons Diffraction RX Etude expérimentale Hétérocycle soufre phosphore Isomérisation Mécanisme réaction Phosphore Composé organique Photolyse Rayonnement UV proche Structure cristalline Structure moléculaire Sulfure organique 1,3Thiaphosphole-4,5-dicaboxylique acide(2-[bis(diisopropylamino)thiophosphoryl]-3,3-bis[diisopropylamino]) ester diméthyle Méthane(di[bis(diisopropylamino)thiophosphoryl] diazo)
Keyword (en)
Organic compounds Five membered ring X ray diffraction Experimental study Sulfur phosphorus heterocycle Isomerization Reaction mechanism Phosphorus Organic compounds Photolysis Near ultraviolet radiation Crystalline structure Molecular structure Organic sulfide
Keyword (es)
Compuesto orgánico Ciclo 5 eslabones Difracción RX Estudio experimental Heterociclo azufre fósforo Isomerización Mecanismo reacción Fósforo Compuesto orgánico Fotolisis Radiación ultravioleta próxima Estructura cristalina Estructura molecular Sulfuro orgánico
Classification
Pascal
001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66H Organic compounds / 001B60A66H1 Organometalloidal and organometallic compounds

Pascal
001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry

Discipline
General chemistry and physical chemistry Physics of condensed state : structure, mechanical and thermal properties
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
5358424

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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