Pentaenyl cations from the photolysis of retinyl acetate. Solvent effects on the leaving group ability and relative nucleophilicities : an unequivocal and quantitative demonstration of the importance of hydrogen bonding
- Author
- PIENTA, N. J; KESSLER, R. J
Univ. North Carolina, dep. chemistry, Chapel Hill NC 27599-3290, United States - Source
Journal of the American Chemical Society. 1992, Vol 114, Num 7, pp 2419-2428 ; ref : 35 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Cation organique Composé aliphatique Composé monocyclique Composé polyénique conjugué Constante vitesse Effet solvant Ester Intermédiaire réaction Liaison hydrogène Mécanisme SN1 Mécanisme SN2 Photolyse Spectrométrie absorption Acétique acide ester rétinyle
- Keyword (en)
- Organic cation Aliphatic compound Monocyclic compound Conjugated polyenic compound Rate constant Solvent effect Ester Reaction intermediate Hydrogen bond SN1 mechanism SN2 mechanism Photolysis Absorption spectrometry
- Keyword (es)
- Catión orgánico Compuesto alifático Compuesto monocíclico Compuesto poliénico conjugado Constante velocidad Efecto solvente Ester Intermediario reacción Enlace hidrógeno Mecanismo SN1 Mecanismo SN2 Fotolisis Espectrometría absorción
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry
- Discipline
- General chemistry and physical chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 5358734
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja00033a017 
https://dx.doi.org/10.1021/ja00033a017
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