Photochemical substitution reactions of [CpFe(CO)2]2 (Cp = η5-C5H5) in hydrocarbon and tetrahydrofuran solution at room temperature : a mechanistic study with time-resolved infrared spectroscopy
- Author
- DIXON, A. J; GEORGE, M. W; HUGHES, C; POLIAKOFF, M; TURNER, J. J
Univ. Nottingham, dep. cheistry, Nottingham Notts., United Kingdom - Source
Journal of the American Chemical Society. 1992, Vol 114, Num 5, pp 1719-1729 ; ref : 53 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Complexe dinucléaire Complexe hapto Composé monocyclique Constante vitesse Cycle 5 chaînons Fer Carbonyle Complexe Hétérocycle oxygène Intermédiaire réaction Liaison métal métal Métal transition Carbonyle Complexe Phosphore Composé organique Photolyse Rayonnement UV proche Rayonnement visible Rendement quantique Réaction photochimique Résolution temporelle Spectrométrie IR Substitution chimique Fer(η5-cyclopentadiényl) complxe Furane(tétrahydro) Phosphite(trialkyl)
- Keyword (en)
- Dinuclear complex Hapto complex Monocyclic compound Rate constant Five membered ring Iron Carbonyl Complexes Oxygen heterocycle Reaction intermediate Metal metal bond Transition metal Carbonyl Complexes Phosphorus Organic compounds Photolysis Near ultraviolet radiation Visible radiation Quantum yield Photochemical reaction Time resolution Infrared spectrometry Chemical substitution
- Keyword (es)
- Complejo dinuclear Complejo hapto Compuesto monocíclico Constante velocidad Ciclo 5 eslabones Hierro Carbonilo Complejo Heterociclo oxígeno Intermediario reacción Enlace metal metal Metal transición Carbonilo Complejo Fósforo Compuesto orgánico Fotolisis Radiación ultravioleta próxima Radiacion invisible Rendimiento quántico Reacción fotoquímica Resolución temporal Espectrometría IR Sustitución química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry
- Discipline
- General chemistry and physical chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 5400328
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja00031a027 
https://dx.doi.org/10.1021/ja00031a027
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