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Rutheniuminduzierter Abbau von Tetramethylthioharstoff zu Carbin- und Dicarbenliganden. Synthese und Molekülstruktur der Cluster Ru4(CO)102-CNMe2)(μ3-S)[μ3-SRu(CO)32-CH2NMeCNMe2)], Ru5(CO)112-CNMe2)24-S)2 und Ru42-CO)3(CO)64-S)22-Me2NCNMeCH2CNMe2)

Other title
Ruthenium induced degradation of tetramethylthiourea to carbyne and dicarbene ligands. Synthesis and molecular structure of clusters Ru4(CO)102-CNMe2)(μ3-S)[μ3-SRu(CO)32-CH2NMeCNMe2)], Ru5(CO)112-CNMe2)24-S)2 and Ru42-CO)3(CO)64-S)22-Me2NCNMeCH2CNMe2) (en)
Author
BODENSIECK, U; STOECKLI-EVANS, H; RHEINWALD, G; SÜSS-FINK, G
Univ. Neuchâtel, Inst. Chimie, 2000 Neuchâtel, Switzerland
Source

Journal of organometallic chemistry. 1992, Vol 433, Num 1-2, pp 167-182 ; ref : 12 ref

CODEN
JORCAI
ISSN
0022-328X
Scientific domain
Organic chemistry; Crystallography
Publisher
Elsevier Science, Lausanne
Publication country
Switzerland
Document type
Article
Language
German
Keyword (fr)
Agrégat complexe Carbyne Carbène Complexe hapto Complexe mu Complexe polynucléaire Complexe sulfuro Complexe tétranucléaire Complexe ylidène Coordinat organique Liaison métal métal Métal transition Carbonyle Complexe Métallocycle Platinoïde Carbonyle Complexe Pyrolyse Ruthénium Carbonyle Complexe Ruthénium Composé organique 1-Aza-3-ruthénacyclobut-2-ène(2-diméthylamino-1-méthyl) complexe 1-Aza-3-ruthénacyclopenta-2,3-diène(2,4-bis[diméthylamino]-1-méthyl) complexe Diffraction RX Etude expérimentale Méthylidyne(diméthylamino) Structure cristalline Structure moléculaire Thiourée(tétraméthyl) Triruthénium dodécacarbonyle
Keyword (en)
Complex cluster Carbyne Carbene Hapto complex Mu complex Polynuclear complex Thio complex Tetranuclear complex Ylidene complex Organic ligand Metal metal bond Transition metal Carbonyl Complexes Metallocycle Platinoid Carbonyl Complexes Pyrolysis Ruthenium Carbonyl Complexes Ruthenium Organic compounds
Keyword (es)
Agregado complejo Carbino Carbeno Complejo hapto Complejo mu Complejo polinuclear Complejo sulfuro Complejo tetranuclear Complejo ilideno Ligando orgánico Enlace metal metal Metal transición Carbonilo Complejo Metalociclo Platinoide Carbonilo Complejo Pirólisis Rutenio Carbonilo Complejo Rutenio Compuesto orgánico
Classification
Pascal
001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66H Organic compounds / 001B60A66H1 Organometalloidal and organometallic compounds

Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C01 Organometalloidal and organometallic compounds / 001C03C01H Transition metals derivatives

Discipline
Organic chemistry Physics of condensed state : structure, mechanical and thermal properties
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
5424573

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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