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Photochemical reaction of Rh2(CO)4(μ-TPP)(TPP=tetraphenylporphyrinato) with pyridine (Py) in benzene. Generation of a mononuclear rhodium(II) porphyrin radical complex Rh(TPP)(Py)

Author
JIN-WAN HUANG; LIANG-NIAN JI; AN-KONG HSICH; ANDY HOR, T. S
Zhongshan univ., dep. chemistry, Guangzhou, China
Source

Transition metal chemistry (Weinheim). 1992, Vol 17, Num 4, pp 280-282 ; ref : 11 ref

CODEN
TMCHDN
ISSN
0340-4285
Scientific domain
Inorganic chemistry
Publisher
Springer, Dordrecht
Publication country
Netherlands
Document type
Article
Language
English
Keyword (fr)
Complexe dinucléaire Complexe mu Coordinat organique Décarbonylation Hétérocycle azote Macrocycle Photolyse Porphyrine métallique Pyridine Radical libre Rendement quantique Rhodium Carbonyle Complexe Porphyrine(5,10,15,20-tétraphényl) Complexe Mixte Métal transition Carbonyle Complexe Platinoïde Complexe
Keyword (en)
Dinuclear complex Mu complex Organic ligand Decarbonylation Nitrogen heterocycle Macrocycle Photolysis Metalloporphyrin Pyridine Free radical Quantum yield Rhodium Carbonyl Complexes Complexes Mixed Transition metal Carbonyl Complexes Platinoid Complexes
Keyword (es)
Complejo dinuclear Complejo mu Ligando orgánico Descarbonilación Heterociclo nitrógeno Macrociclo Fotolisis Porfirina metálica Piridina Radical libre Rendimiento quántico Rodio Carbonilo Complejo Complejo Mixto Metal transición Carbonilo Complejo Platinoide Complejo
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry

Discipline
General chemistry and physical chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
5462667

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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