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Additions of chiral allyltitanocenes to aldehydes: diastereoselective synthesis of homoallylic alcohols with a recyclable chiral transition metal reagent

Author
COLLINS, S1 ; KUNTZ, B. A; HONG, Y
[1] Guelph-Waterloo cent. graduate work chemistry, Waterloo ON N2L 3G1, Canada
Source

Journal of organic chemistry. 1989, Vol 54, Num 17, pp 4154-4158 ; ref : 21 ref

CODEN
JOCEAH
ISSN
0022-3263
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Addition chimique Alcool secondaire Aldéhyde Complexe chloro Complexe hapto Composé aliphatique Composé homoallylique Composé sandwich Diastéréosélectivité Métal transition Complexe Titane Complexe Titane Composé organique Hexène-5 ol-3(diméthyl-«2,2») Magnésium(butène-«2» yl) chlorure Titane(tétrahydro-«4,5,6,7» [tétrahydro-«4,5,6,7» indényl-«1»]-«2p» éthyl-«1») complexe
Keyword (en)
Addition reaction Secondary alcohol Aldehyde Chloro complex Hapto complex Aliphatic compound Homoallylic compound Sandwich compound Diastereoselectivity Transition metal Complexes Titanium Complexes Titanium Organic compounds
Keyword (es)
Adición química Alcohol secundario Aldehído Complejo cloro Complejo hapto Compuesto alifático Compuesto homoalílico Compuesto sandwich Diastereoselectividad Metal transición Titanio Titanio
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C02 Aliphatic compounds

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
6590360

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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