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13C dynamic NMR studies on restricted rotation about C-N bond in 2-aryl-1-formyl-4-piperidones

Author
RUBIRALTA, M1 ; PILAR MARCO, M; FELIZ, M; GIRALT, E
[1] Univ. Barcelona, fac. pharmacy, lab. organic chemistry, Barcelona 08028, Spain
Source

Heterocycles (Sendai). 1989, Vol 29, Num 11, pp 2185-2192 ; ref : 21 ref

CODEN
HTCYAM
ISSN
0385-5414
Scientific domain
Organic chemistry
Publisher
Elsevier, Oxford
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Acétal Barrière rotation Carboxamide Composé aromatique Composé bicyclique Conformation Cycle 6 chaînons Cétone Energie libre Etude expérimentale Hétérocycle azote Propriété thermodynamique Préparation Spectre RMN Carbone 13 Dioxa-«1,4»aza-«8»spiro [«4.5»] décanecarbaldéhyde-8([indolyl-«3»]-«7» méthyl-«6») Pipéridinecarbaldéhyde-1([indolyl-3]-«2» oxo-«4»)
Keyword (en)
Acetal Rotation barrier Carboxamide Aromatic compound Bicyclic compound Conformation Six membered ring Ketone Free energy Experimental study Nitrogen heterocycle Thermodynamic properties Preparation NMR spectrum
Keyword (es)
Acetal Barrera rotación Carboxamida Compuesto aromático Compuesto bicíclico Conformación Ciclo 6 eslabones Cetona Energía libre Estudio experimental Heterociclo nitrógeno Propiedad termodinámica Preparación Espectro de RMN
Classification
Pascal
001 Exact sciences and technology / 001B Physics / 001B30 Atomic and molecular physics / 001B30C Molecular properties and interactions with photons / 001B30C15 Properties of molecules and molecular ions / 001B30C15H Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics)

Discipline
Atomic and molecular physics
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
6635621

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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