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Aldol reactions in polypropionate synthesis: high π-face selectivity of enol borinates from α-chiral methyl and ethyl ketones under substrate control

Author
PATERSON, I1 ; GOODMAN, J. M; ISAKA, M
[1] Univ. chemical lab., Cambridge CB2 1EW, United Kingdom
Source

Tetrahedron letters. 1989, Vol 30, Num 50, pp 7121-7124 ; ref : 12 ref

CODEN
TELEAY
ISSN
0040-4039
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
Elsevier, Oxford
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Aldolisation Aldéhyde Bore Composé organique Borinate organique Composé aliphatique Composé saturé Cétone Stéréosélectivité Borane(chloro dicyclohexyl) Borane(dicyclohexyl trifluoromésyloxy) Octène-«6»one-3(benzyloxyméthyl-«2» hydroxy-«5» méthyl-«4») Pentanone-3(benzyloxyméthyl-«2») Propénal(méthyl-2)
Keyword (en)
Aldol condensation Aldehyde Boron Organic compounds Organic borinate Aliphatic compound Saturated compound Ketone Stereoselectivity
Keyword (es)
Aldolización Aldehído Boro Borinato orgánico Compuesto alifático Compuesto saturado Cetona Estereoselectividad
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C02 Aliphatic compounds

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
6688088

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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