Homogeneous catalysis of silane alcoholysis via nucleophilic attack by the alcohol on an Ir(η2-HSiR3) intermediate catalyzed by [IrH2S2(PPh3)2]SbF6 (S=solvent)
- Author
- XIAO-LIANG LUO1 ; CRABTREE, R. H
[1] Yale univ., dep. chemistry, New Haven CT 06511, United States - Source
Journal of the American Chemical Society. 1989, Vol 111, Num 7, pp 2527-2535 ; ref : 46 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Alcoolyse Complexe dihydrogène Constante vitesse Coordinat organique Intermédiaire réaction Iridium Complexe Réaction catalytique Silane organique Silicium Composé organique Alcanol Silane(triéthyl) Triphénylphosphine
- Keyword (en)
- Alcoholysis Dihydrogen complex Rate constant Organic ligand Reaction intermediate Iridium Complexes Catalytic reaction Organic silane Silicon Organic compounds
- Keyword (es)
- Alcoholisis Complejo dihidrógeno Constante velocidad Ligando orgánico Intermediario reacción Iridio Reacción catalítica Silano orgánico Silicio
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 6775028
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja00189a026 
https://dx.doi.org/10.1021/ja00189a026
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