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A short enantioselective synthesis of (+)-sterpurene: complete intramolecular transfer of central to axial to central chiral elements

Author
GIBBS, R. A1 ; OKAMURA, W. H
[1] Univ. California, dep. chemistry, Riverside CA 92521, United States
Source

Journal of the American Chemical Society. 1988, Vol 110, Num 12, pp 4062-4063 ; ref : 21 ref

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Addition Diels Alder Alcool secondaire Composé aliphatique Composé monocyclique Composé tricyclique Composé énynique Composé éthylénique Enantiomère(+) Enantiosélectivité Hydrocarbure Réaction intramoléculaire Sesquiterpène Heptène-6yne-«1»ol-3(diméthyl-«4,4» méthyl-«2p» cyclobutène-«1p» yl-«1») Heptène-«6»yne-«1»ol-3(diméthyl-«4,4») Sterpurène
Keyword (en)
Diels Alder addition Secondary alcohol Aliphatic compound Monocyclic compound Tricyclic compound Enynic compound Ethylenic compound Enantiomer(+) Enantioselectivity Hydrocarbon Intramolecular reaction Sesquiterpenes
Keyword (es)
Adición Diels Alder Alcohol secundario Compuesto alifático Compuesto monocíclico Compuesto tricíclico Compuesto enínico Compuesto etilénico Enantiómero (+) Enantioselectividad Hidrocarburo Reacción intramolecular Sesquiterpeno
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
7200704

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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