Theoretical calculation of effects of steric hindrance on rates of esterification and of acid-catalyzed hydrolysis
- Author
- DE TAR, D. L. F1 ; BINZET, S; DARBA, P
[1] Florida state univ., dep. chemistry, Tallahassee FL 32306, United States - Source
Journal of organic chemistry. 1987, Vol 52, Num 10, pp 2074-2082 ; ref : 73 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Acide carboxylique Catalyse acide Composé aliphatique Composé saturé Constante vitesse Effet stérique Effet substituant Energie libre Estérification Etude théorique Hydrolyse Intermédiaire réaction Méthode champ force Propriété thermodynamique Relation linéaire Acide alcanoïque
- Keyword (en)
- Carboxylic acid Acid catalysis Aliphatic compound Saturated compound Rate constant Steric effect Substituent effect Free energy Esterification Theoretical study Hydrolysis Reaction intermediate Force field method Thermodynamic properties Linear relation
- Keyword (es)
- Acido carboxílico Catálisis ácida Compuesto alifático Compuesto saturado Constante velocidad Efecto estérico Efecto sustituyente Energía libre Esterificación Estudio teórico Hidrólisis Intermediario reacción Método campo fuerza Propiedad termodinámica Relación lineal
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 7391633
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo00386a032 
https://dx.doi.org/10.1021/jo00386a032
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