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Total synthesis of (-)-laurenyne: use of acetal-initiated cyclizations to prepare functionalized eight-membered cyclic ethers

Author
OVERMAN, L. E1 ; THOMPSON, A. S
[1] Univ. California, dep. chemistry, Irvine CA 92717, United States
Source

Journal of the American Chemical Society. 1988, Vol 110, Num 7, pp 2248-2256 ; ref : 50 ref

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Acétal Composé aliphatique Composé énynique Cycle 8 chaînons Cyclisation Enantiomère(-) Hétérocycle oxygène Spectre IR Spectre RMN Spectre masse Butanal(t-butyldiphénylsiloxy-«4»)[(chloro-«2p» tosyloxyméthyl-«1p» triméthylsilyl-«5p») hexène-«5p» yl éthyl] acétal Carbone 13 Hydrogène 1 Laurényne Oxocinne dérivé
Keyword (en)
Acetal Aliphatic compound Enynic compound Eight membered ring Cyclization Enantiomer(-) Oxygen heterocycle Infrared spectrum NMR spectrum Mass spectrum
Keyword (es)
Acetal Compuesto alifático Compuesto enínico Ciclo 8 eslabones Ciclización Enantiómero(-) Heterociclo oxígeno Espectro IR Espectro de RMN Espectro masa
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06A Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
7585384

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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