Prediction and experimental verification of the stereoselective electrocyclization of 3-formylcyclobutene
- Author
- RUDOLF, K1 ; SPELLMEYER, D. C; HOUK, K. N
[1] Univ. California Los Angeles, dep. chemistry biochemistry, Los Angeles CA 90024, United States - Source
Journal of organic chemistry. 1987, Vol 52, Num 16, pp 3708-3710 ; ref : 11 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Composé aliphatique Composé diénique conjugué Composé monocyclique Composé éthylénique Conformation Décyclisation Effet substituant Energie activation Etat transition Etude théorique Méthode ab initio Orbitale frontière Orbitale gaussienne Rotation interne Réaction électrocyclique Stéréosélectivité Aldéhyde Butadiène-«2,4»al Cyclobutène-2carbaldéhyde
- Keyword (en)
- Aliphatic compound Conjugated dienic compound Monocyclic compound Ethylenic compound Conformation Ring cleavage Substituent effect Activation energy Transition state Theoretical study Ab initio method Frontier orbital Gaussian orbital Internal rotation Electrocyclic reaction Stereoselectivity
- Keyword (es)
- Compuesto alifático Compuesto diénico conjugado Compuesto monocíclico Compuesto etilénico Conformación Deciclización Efecto sustituyente Energía activación Estado transitorio Estudio teórico Método ab initio Orbital frontera Orbital gaussiano Rotación interna Reacción electrocíclica Estereoselectividad
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B01 Chemical reactivity
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 7623734
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo00392a047 
https://dx.doi.org/10.1021/jo00392a047
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