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Titanium(IV)-chloride-catalyzed reactions of rotameric 3-(1,4-dimethoxy-9-triptycyl)-3-methylbutanoyl chloride. Isolation of two rotameric ketones and competition between cyclization and lactone formation

Author
OKI, M1 ; TANAKA, T; YAMAMOTO, G
[1] Univ. Tokyo, fac. sci., dep. chemistry, Bunkyo-ku Tokyo 113, Japan
Source

Chemistry Letters. 1987, Num 9, pp 1815-1818 ; ref : 10 ref

CODEN
CMLTAG
ISSN
0366-7022
Scientific domain
Chemistry; Atomic molecular physics
Publisher
Chemical Society of Japan, Tokyo
Publication country
Japan
Document type
Article
Language
English
Keyword (fr)
Barrière rotation Chlorure acyle Composé aromatique Composé pentacyclique Composé polycyclique Conformation Cyclisation Hétérocycle oxygène Lactone Méthode champ force Stéréoisomère Titane IV Chlorure Benzéno anthra pyranne dérivé Benzéno benzo anthracène dérivé Triptycènepropionique-9 acide(diméthoxy-«1,4» «β,β»-diméthyl) chlorure
Keyword (en)
Rotation barrier Acyl chloride Aromatic compound Pentacyclic compound Polycyclic compound Conformation Cyclization Oxygen heterocycle Lactone Force field method Stereoisomer Titanium IV Chlorides
Keyword (es)
Barrera rotación Cloruro acilo Compuesto aromático Compuesto pentacíclico Compuesto policíclico Conformación Ciclización Heterociclo oxígeno Lactona Método campo fuerza Estereoisómero Titanio IV
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05A Alicyclic compounds

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
7637428

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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