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The syntheses and crystal and molecular structures of some ten-vertex (MCB8; M=Ru or Os) metallacarbaboranes: 9,9,9-(CO)(PPh3)2-nido-9,6-MCB8-H10-5-(PPh3)] (M=Ru or Os) and [9,9,9-(η-C5H5)(H)(PPh3)-arachno-9,6-Ru-CB8H12]

Author
ALCOCK, N. W1 ; JASZTAL, M. J; WALLBRIDGE, M. G. H
[1] Univ. Warwick, dep. chemistry, Coventry CV4 7AL, United Kingdom
Source

Journal of the Chemical Society. Dalton transactions. 1987, Num 11, pp 2793-2802 ; ref : 25 ref

CODEN
JCDTBI
ISSN
0300-9246
Scientific domain
Inorganic chemistry; Crystallography; Atomic molecular physics
Publisher
Royal Society of Chemistry, Cambridge
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Complexe hapto Complexe hydruro Composé benzénique Composé minéral Coordinat organique Diffraction RX Etude expérimentale Métal transition Composé Métallocarborane Osmium Carbonyle Complexe Osmium Composé organique Paramètre RMN Phosphine organique Phosphine tertiaire Ruthénium Carbonyle Complexe Ruthénium Complexe Ruthénium Composé organique Solution chimique Structure cristalline Structure moléculaire Bore 11 Carba-6ruthéna-«9»nido-décaborane(«11») (triphénylphosphino-«5») complexe Carba-«6»osmo-«9»nido-décaborane(«11») (triphénylphosphino-«5») complexe Carba-«6»ruthéno-«9»arachnodécaborane(«12») complexe Hydrogène 1 Ruthénium(«η5»-cyclopentadiényl) complexe Spectre RMN Triphénylphosphine
Keyword (en)
Hapto complex Hydrido complex Benzenic compound Inorganic compound Organic ligand X ray diffraction Experimental study Transition metal Compounds Metallocarborane Osmium Carbonyl Complexes Osmium Organic compounds NMR parameter Organic phosphine Tertiary phosphine Ruthenium Carbonyl Complexes Ruthenium Complexes Ruthenium Organic compounds Chemical solution Crystalline structure Molecular structure
Keyword (es)
Complejo hapto Complejo hidruro Compuesto bencénico Compuesto mineral Ligando orgánico Difracción RX Estudio experimental Metal transición Metalocarborano Osmio Osmio Parámetro RMN Fosfina orgánica Fosfina terciaria Rutenio Rutenio Rutenio Solución química Estructura cristalina Estructura molecular
Classification
Pascal
001 Exact sciences and technology / 001B Physics / 001B60 Condensed matter: structure, mechanical and thermal properties / 001B60A Structure of solids and liquids; crystallography / 001B60A66 Structure of specific crystalline solids / 001B60A66F Inorganic compounds / 001B60A66F6 Carbonyl and nitrosyl compounds, and their complexes

Discipline
Physics of condensed state : structure, mechanical and thermal properties
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
7768818

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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