Direct observation of the reverse 1,5-hydride shift: the mechanism of acid-catalyzed isomerization at C-25 of spirostanols
- Author
- SEO, S1 ; UOMORI, A; TAKEDA, K
[1] Shionogi & co. ltd., Fukushima-ku Osaka 553, Japan - Source
Journal of organic chemistry. 1986, Vol 51, Num 20, pp 3823-3827 ; ref : 13 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Catalyse acide Cycle 5 chaînons Cycle 6 chaînons Deutérium Ethanol Hydrogène Isotope Hydrogénation Hétérocycle oxygène Isomérisation Marquage isotopique Perchlorique acide Réaction catalytique Spirane Stéroide Acétique acide,ester éthyle Borane(trifluoro) Diosgénine,acétate Furostane-5αdiol-3β,26,acétate Furostane-«5α»al-26(acétoxy-«3β») Spirostane dérivé Tigogénine
- Keyword (en)
- Acid catalysis Five membered ring Six membered ring Deuterium Ethanol Hydrogen Isotopes Hydrogenation Oxygen heterocycle Isomerization Isotope labelling Perchloric acid Catalytic reaction Spiran Steroid
- Keyword (es)
- Catálisis ácida Ciclo 5 eslabones Ciclo 6 eslabones Deuterio Etanol Hidrógeno Hidrogenacion Heterociclo oxígeno Isomerizacion Marcaje isotopico Perclórico ácido Reacción catalítica Espirano Esteroide
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B05 Labelled compounds chemistry
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 7990349
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo00370a014 
https://dx.doi.org/10.1021/jo00370a014
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