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Direct observation of the reverse 1,5-hydride shift: the mechanism of acid-catalyzed isomerization at C-25 of spirostanols

Author
SEO, S1 ; UOMORI, A; TAKEDA, K
[1] Shionogi & co. ltd., Fukushima-ku Osaka 553, Japan
Source

Journal of organic chemistry. 1986, Vol 51, Num 20, pp 3823-3827 ; ref : 13 ref

CODEN
JOCEAH
ISSN
0022-3263
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Catalyse acide Cycle 5 chaînons Cycle 6 chaînons Deutérium Ethanol Hydrogène Isotope Hydrogénation Hétérocycle oxygène Isomérisation Marquage isotopique Perchlorique acide Réaction catalytique Spirane Stéroide Acétique acide,ester éthyle Borane(trifluoro) Diosgénine,acétate Furostane-5αdiol-3β,26,acétate Furostane-«5α»al-26(acétoxy-«3β») Spirostane dérivé Tigogénine
Keyword (en)
Acid catalysis Five membered ring Six membered ring Deuterium Ethanol Hydrogen Isotopes Hydrogenation Oxygen heterocycle Isomerization Isotope labelling Perchloric acid Catalytic reaction Spiran Steroid
Keyword (es)
Catálisis ácida Ciclo 5 eslabones Ciclo 6 eslabones Deuterio Etanol Hidrógeno Hidrogenacion Heterociclo oxígeno Isomerizacion Marcaje isotopico Perclórico ácido Reacción catalítica Espirano Esteroide
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B05 Labelled compounds chemistry

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
7990349

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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