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Direct and sensitized valence photoisomerization of a substituted norbornadiene. Examination of the disparity between singlet- and triplet-state reactivities

Author
IKEZAWA, H1 ; KUTAL, C; YASUFUKU, K; YAMAZAKI, H
[1] Univ. Georgia, dep. chemistry, Athens GA 30602, United States
Source

Journal of the American Chemical Society. 1986, Vol 108, Num 7, pp 1589-1594 ; ref : dissem

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Cinétique Complexe cationique Composé bicyclique Composé polycyclique Coordinat organique Cycle 6 chaînons Effet substituant Etat singulet Etat triplet Hétérocycle azote Isomérisation valence Photolyse UV Photosensibilisant Rendement quantique Ruthénium II Complexe Spectre visible Biacétyle Bipyridyle-«2,2p» Fluorénone-9 Norbornadiènedicarbonitrile-2,3(triméthyl-«1,5,6») Quadricyclanedicarbonitrile-1,5(triméthyl-«2,6,7»)
Keyword (en)
Kinetics Cationic complex Bicyclic compound Polycyclic compound Organic ligand Six membered ring Substituent effect Singlet state Triplet state Nitrogen heterocycle Valence isomerization Ultraviolet photolysis Photosensitizer Quantum yield Ruthenium II Complexes Visible spectrum
Keyword (es)
Cinetica Complejo catiónico Compuesto bicíclico Compuesto policíclico Ligando orgánico Ciclo 6 eslabones Efecto sustituyente Estado singular Estado triple Heterociclo nitrógeno Isomerización valencia Fotolisis UV Fotosensibilizante Rendimiento quantico Rutenio II Espectro visible
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry

Discipline
General chemistry and physical chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
7998747

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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