Direct and sensitized valence photoisomerization of a substituted norbornadiene. Examination of the disparity between singlet- and triplet-state reactivities
- Author
- IKEZAWA, H1 ; KUTAL, C; YASUFUKU, K; YAMAZAKI, H
[1] Univ. Georgia, dep. chemistry, Athens GA 30602, United States - Source
Journal of the American Chemical Society. 1986, Vol 108, Num 7, pp 1589-1594 ; ref : dissem
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Cinétique Complexe cationique Composé bicyclique Composé polycyclique Coordinat organique Cycle 6 chaînons Effet substituant Etat singulet Etat triplet Hétérocycle azote Isomérisation valence Photolyse UV Photosensibilisant Rendement quantique Ruthénium II Complexe Spectre visible Biacétyle Bipyridyle-«2,2p» Fluorénone-9 Norbornadiènedicarbonitrile-2,3(triméthyl-«1,5,6») Quadricyclanedicarbonitrile-1,5(triméthyl-«2,6,7»)
- Keyword (en)
- Kinetics Cationic complex Bicyclic compound Polycyclic compound Organic ligand Six membered ring Substituent effect Singlet state Triplet state Nitrogen heterocycle Valence isomerization Ultraviolet photolysis Photosensitizer Quantum yield Ruthenium II Complexes Visible spectrum
- Keyword (es)
- Cinetica Complejo catiónico Compuesto bicíclico Compuesto policíclico Ligando orgánico Ciclo 6 eslabones Efecto sustituyente Estado singular Estado triple Heterociclo nitrógeno Isomerización valencia Fotolisis UV Fotosensibilizante Rendimiento quantico Rutenio II Espectro visible
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry
- Discipline
- General chemistry and physical chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 7998747
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja00267a032 
https://dx.doi.org/10.1021/ja00267a032
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