The radical anion of homoazulene and its rearrangement products. An ESR and ENDOR study
- Author
- GERSON, F1 ; KNÖBEL, J; METZGER, A; SCOTT, L. T; KIRMS, M. A; ODA, M; SUMPTER, C. A
[1] Univ. Basel, inst. physikalische chemie, Basel 4056, Switzerland - Source
Journal of the American Chemical Society. 1986, Vol 108, Num 25, pp 7920-7926 ; ref : 37 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Composé bicyclique Composé marqué Constante couplage hyperfin Deutérium Dépolarisation spin Homoconjugaison Hydrogène Isotope Orbitale antiliante Polarisation spin Potentiel demi vague Radical libre organique anionique Réduction chimique Solution chimique Spectre ENDOR Spectre RPE Transposition chimique Benzo cycloheptényle dianion Cyclopenta cyclooctényle dianion Méthano-1,5 [«10»] annulénylure
- Keyword (en)
- Bicyclic compound Labelled compound Hyperfine coupling constant Deuterium Spin depolarization Homoconjugation Hydrogen Isotopes Antibonding orbital Spin polarization Half wave potential Organic radical anion Chemical reduction Chemical solution ENDOR spectrum EPR spectrum Chemical rearrangement
- Keyword (es)
- Compuesto bicíclico Compuesto marcado Constante acoplamiento hiperfino Deuterio Despolarización spin Homoconjugación Hidrógeno Orbital antiligante Polarización spin Potencial media onda Radical libre orgánico aniónico Reducción química Solución química Espectro ENDOR Espectro RPE Transposición química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B04 Free radicals chemistry
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 8001842
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja00285a007 
https://dx.doi.org/10.1021/ja00285a007
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