The observation of four separate fluxional processes in [Re3(CO)10H3]2-, including an example of the rotation of an Re≡Re fragment on ReH(CO)4
- Author
- BERINGHELLI, T1 ; D'ALFONSO, G; MOLINARI, H; MANN, B. E; PICKUP, B. T; SPENCER, C. M
[1] Cent. studio sintesi struttura composti metalli transizione bassi stati ossidazione, Milano 20133, Italy - Source
Journal of the Chemical Society. Chemical communications. 1986, Num 10, pp 796-798 ; ref : 6 ref
- CODEN
- JCCCAT
- ISSN
- 0022-4936
- Scientific domain
- Chemistry; Crystallography; Atomic molecular physics
- Publisher
- Royal Society of Chemistry, Cambridge
- Publication country
- United Kingdom
- Document type
- Article
- Language
- English
- Keyword (fr)
- Complexe anionique Complexe hydruro Complexe mu Complexe trinucléaire Comportement fluxionnel Composé minéral Etude expérimentale Liaison métal métal Rhénium Carbonyle Complexe Rotation interne Solution chimique Spectre RMN Séquence impulsion Séquence DANTE Transfert magnétisation Carbone 13
- Keyword (en)
- Anionic complex Hydrido complex Mu complex Trinuclear complex Fluxional behavior Inorganic compound Experimental study Metal metal bond Rhenium Carbonyl Complexes Internal rotation Chemical solution NMR spectrum Pulse sequence
- Keyword (es)
- Complejo aniónico Complejo hidruro Complejo mu Complejo trinuclear Comportamiento variable Compuesto mineral Estudio experimental Enlace metal metal Renio Rotación interna Solución química Espectro de RMN Secuencia impulsos
- Classification
- Pascal
- 001 Exact sciences and technology / 001B Physics / 001B30 Atomic and molecular physics / 001B30C Molecular properties and interactions with photons / 001B30C15 Properties of molecules and molecular ions / 001B30C15H Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics)
- Discipline
- Atomic and molecular physics
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 8054962
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1039/C39860000796 
https://dx.doi.org/10.1039/C39860000796
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