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Diastereoselective π-facialy controlled nucleophilic of chiral vinylorgano-metallics to chiral β,γ-unsaturated ketones. II: A practical method for stereocontrolled elaboration of the decahydro-as-indacene subunit of ikarugamycin

Author
PAQUETTE, L. A1 ; ROMINE, J. L; LIN, H.-S
[1] Ohio state univ., Evans Chemical Laboratories, Columbus OH 43210, United States
Source

Tetrahedron letters. 1987, Vol 28, Num 1, pp 31-34 ; ref : 15 ref

CODEN
TELEAY
ISSN
0040-4039
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
Elsevier, Oxford
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Acétal Addition chimique Ammoniac Composé bicyclique Composé insaturé Composé monocyclique Composé tricyclique Cétone Diastéréosélectivité Hydrocarbure bromé Lithium Réaction nucléophile Réduction chimique Cyclopentène(bromo-«2» éthyl-«3» méthyl-«4») Ikarugamycine Indacène dérivé Norbornène-5dione-2,7,diméthylacétal-7
Keyword (en)
Acetal Addition reaction Ammonia Bicyclic compound Unsaturated compound Monocyclic compound Tricyclic compound Ketone Diastereoselectivity Bromocarbon Lithium Nucleophilic reaction Chemical reduction
Keyword (es)
Acetal Adición química Amoniaco Compuesto bicíclico Compuesto insaturado Compuesto monocíclico Compuesto tricíclico Cetona Diastereoselectividad Hidrocarburo bromado Litio Reacción nucléofila Reducción química
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05A Alicyclic compounds

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
8095828

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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