Thermal decomposition of α-diazo-α-(trialkylsilyl)alkanones: intramolecular C/H insertion of siloxyalkylidenecarbene intermediates
- Author
- BRÜCKMANN, R1 ; MAAS, G
[1] Univ. Kaiserslautern, fachbereich chemie, Kaiserslautern 6700, Germany - Source
Chemische Berichte. 1987, Vol 120, Num 4, pp 635-641 ; ref : 36 ref
- CODEN
- CHBEAM
- ISSN
- 0009-2940
- Scientific domain
- Chemistry; Organic chemistry; Crystallography
- Publisher
- VCH, Basel
/
VCH, Cambridge
/
VCH, Weinheim
- Publication country
- Germany
- Document type
- Article
- Language
- English
- Keyword (fr)
- Composé aliphatique Cycle 5 chaînons Diazocétone Hétérocycle oxygène silicium Mécanisme réaction Pyrolyse Silicium Composé organique Spectre IR Spectre RMN Spectre masse Acétone(diazo-1 triéthylsilyl-«1») Butanone-2(diazo-«1» diméthyl-«3,3» trialkylsilyl-«1») Carbone 13 Hydrogène 1 Oxasilole-«1,2»ène-«4»(alkyl-«5» diisopropyl-«2,2» diméthyl-«3,3») Oxasilole-«1,2»ène-«4»(diéthyl-«2,2» diméthyl-«3,5»)
- Keyword (en)
- Aliphatic compound Five membered ring Diazoketone Oxygen silicon heterocycle Reaction mechanism Pyrolysis Silicon Organic compounds Infrared spectrum NMR spectrum Mass spectrum
- Keyword (es)
- Compuesto alifatico Ciclo 5 eslabones Diazocetona Heterociclo oxígeno silicio Mecanismo de reaccion Pirolisis Silicio Espectro IR Espectro de RMN Espectro masa
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C01 Organometalloidal and organometallic compounds / 001C03C01C Si derivatives
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 8144100
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1002/cber.19871200428 
https://dx.doi.org/10.1002/cber.19871200428
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