Transformations of chiral iron complexes used in organic synthesis. Reactions of η5-CpFe(PPh3)(CO)COCH3 and related species leading to a mild, stereospecific synthesis of β-lactams
- Author
- LIEBESKIND, L. S1 ; WELKER, M. E; FENGL, R. W
[1] Emory univ., dep. chemistry, Atlanta GA 30322, United States - Source
Journal of the American Chemical Society. 1986, Vol 108, Num 20, pp 6328-6343 ; ref : 66 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Aldimine Aldolisation Benzaldéhyde Composé chiral Condensation chimique Coordinat organique Déprotonation Enolate Fer Carbonyle Complexe Fer Composé organique Hétérocycle azote Lactame Métal transition Carbonyle Complexe Stéréosélectivité Synthèse organique Addition chimique Azétidinone-2 dérivé Benzaldéhyde,phénylimine Cycle 4 chaînons Fer(acétyl η5-cyclopentadiényl) complexe Lithium amidure(diisopropyl) THF Triphénylphosphine
- Keyword (en)
- Aldimine Aldol condensation Benzaldehyde Chiral compound Condensation reaction Organic ligand Deprotonation Enolate Iron Carbonyl Complexes Iron Organic compounds Nitrogen heterocycle Lactam Transition metal Carbonyl Complexes Stereoselectivity Organic synthesis
- Keyword (es)
- Aldimina Aldolización Benzaldehído Compuesto quiral Condensación química Ligando orgánico Desprotonacion Enolato Hierro Hierro Heterociclo nitrógeno Lactamo Metal transición Estereoselectividad Síntesis orgánica
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B01 Chemical reactivity
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 8172620
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja00280a034 
https://dx.doi.org/10.1021/ja00280a034
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