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Diastereoselective ene reaction in the photooxygenation of the silyl cyanohydrins of α,β-unsaturated aldehydes: necessity for a common symmetrical intermediate of the perepoxide type

Author
ADAM, W1 ; CATALANI, L. H; GRIESBECK, A
[1] Univ. Würzburg, inst. organische chemie, Würzburg 8700, Germany
Source

Journal of organic chemistry. 1986, Vol 51, Num 26, pp 5494-5496 ; ref : 10 ref

CODEN
JOCEAH
ISSN
0022-3263
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Composé aliphatique Composé éthylénique Diastéréosélectivité Etat singulet Ether Oxygène Oxygénation Réaction photochimique Réaction ène Silicium Composé organique Butène-«3»nitrile(«t»-butyldiméthylsiloxy-«2» hydroperoxy-«1» éthyl-«3») Pentène-3nitrile(méthyl-«4» triméthylsiloxy-«2») Pentène-«3»nitrile(«t»-butyldiméthylsiloxy-«2» méthyl-«3») Pentène-«4»nitrile(hydroxypéroxy-«3» méthyl-«4» triméthylsiloxy-«2»)
Keyword (en)
Aliphatic compound Ethylenic compound Diastereoselectivity Singlet state Ether Oxygen Oxygenation Photochemical reaction Ene reaction Silicon Organic compounds
Keyword (es)
Compuesto alifatico Compuesto etilénico Diastereoselectividad Estado singular Eter Oxígeno Oxigenacion Reacción fotoquímica Reacción ene Silicio
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry

Discipline
General chemistry and physical chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
8228286

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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