Total synthesis of 12α- and 12β-carboxylated estrogens via the thermal elimination of β-ketosulfoxide
- Author
- KUROSAWA, T1 ; NIITSU, U; TOHMA, M
[1] Higashi-Nippon-Gakuen univ., fac. pharmaceutical sci., Ishikari-Tobetsu Hokkaido 061-02, Japan - Source
Chemical and pharmaceutical bulletin. 1987, Vol 35, Num 2, pp 585-592 ; ref : 19 ref
- CODEN
- CPBTAL
- ISSN
- 0009-2363
- Scientific domain
- Organic chemistry; Pharmacology drugs
- Publisher
- Maruzen, Tokyo
- Publication country
- Japan
- Document type
- Article
- Language
- English
- Keyword (fr)
- Addition Michaël Composé aliphatique Composé benzénique Cyclisation Cétoester Cétone Oestrogène Phénols Réduction chimique Stéroide Sulfoxyde Cyclopentanedione-1,3(méthyl-«2») Heptène-2oïque acide(méthoxy-«3p» phényl-«7» oxo-«4») ester méthyle Oestratriène-«1,3,5(10)»carboxylique-12 acide(diacétoxy-3,17) ester méthyle Oestratriène-«1,3,5(10)»carboxylique-12 acide(hydroxy-«3» oxo-«17») ester méthyle Pentanone-2(méthanesulfinyl-«1» méthoxy-«2p» phényl-«5»)
- Keyword (en)
- Michael addition Aliphatic compound Benzenic compound Cyclization Ketoester Ketone Estrogen Phenols Chemical reduction Steroid Sulfoxide
- Keyword (es)
- Adición Michael Compuesto alifatico Compuesto bencénico Ciclizacion Cetoester Cetona Estrogeno Fenoles Reducción química Esteroide Sulfóxido
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05D Steroids
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 8291537
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1248/cpb.35.585 
https://dx.doi.org/10.1248/cpb.35.585
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