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The monocation and monoanion of the Re2(μ-Cl)2(μ-dppm)2Cl4 (dppm=Ph2PCH2PPh2). An unusual pair of complexes possessing metal-metal bond orders of 1.5 that differ in electronic configuration

Author
DUNBAR, K. R1 ; POWELL, D; WALTON, R. A
[1] Purdue univ., dep. chemistry, West Lafayette IN 47907, United States
Source

Journal of the Chemical Society. Chemical communications. 1985, Num 3, pp 114-116 ; ref : 14 ref

CODEN
JCCCAT
ISSN
0022-4936
Scientific domain
Chemistry; Crystallography; Atomic molecular physics
Publisher
Royal Society of Chemistry, Cambridge
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Cobalt Composé organique Complexe cationique Complexe chloro Complexe dinucléaire Complexe mu Composé minéral Coordinat organique Effet milieu Métal transition Complexe Métallocène Nitrosyle Hexafluorophosphate Oxydation Phosphine ditertiaire Phosphore Composé organique Rhénium Complexe Réaction électrochimique Réduction chimique Voltammétrie cyclique Donnée numérique Méthylène bis-diphénylphosphine
Keyword (en)
Cobalt Organic compounds Cationic complex Chloro complex Dinuclear complex Mu complex Inorganic compound Organic ligand Medium effect Transition metal Complexes Metallocene Nitrosyl Hexafluophosphates Oxidation Ditertiary phosphine Phosphorus Organic compounds Rhenium Complexes Electrochemical reaction Chemical reduction Cyclic voltammetry
Keyword (es)
Oxidacion
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01H Electrochemistry / 001C01H05 Kinetics and mechanism of reactions

Discipline
General chemistry and physical chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
9018395

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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