The stereochemistry of the methylenecyclopropane rearrangement: evidence against the orthogonal-allylic intermediate
- Author
- BUCHWALTER, S. L1
[1] Harvard univ., dep. chemistry, Cambridge MA 02138, United States - Source
Tetrahedron (Oxford. Print). 1984, Vol 40, Num 24, pp 5097-5112 ; ref : 37 ref
- CODEN
- TETRAB
- ISSN
- 0040-4020
- Scientific domain
- Organic chemistry
- Publisher
- Elsevier, Oxford
- Publication country
- United Kingdom
- Document type
- Article
- Language
- English
- Keyword (fr)
- Composé chiral Composé monocyclique Composé éthylénique Constante vitesse Diester Dinitrile Inversion configuration Stéréochimie Stéréoisomère anti Stéréoisomère syn Stéréoisomère trans Transposition chimique Cyclopropanedicarbonitrile-1,2(méthylène-3) Cyclopropanedicarboxylique-1,2 acide(méthylène-3) ester diméthyle
- Keyword (en)
- Chiral compound Monocyclic compound Ethylenic compound Rate constant Diester Dinitrile Configuration inversion Stereochemistry Anti stereoisomer Syn stereoisomer Trans stereoisomer Chemical rearrangement
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B01 Chemical reactivity
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 9101141
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1016/S0040-4020(01)91259-1 
https://dx.doi.org/10.1016/S0040-4020(01)91259-1
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