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A NOVEL METHOD FOR INTRODUCTION OF THE ISOPRENE SKELETON INTO CHLOROMETHYLARENES AND -HETEROARENES VIA A THREE-STEP SEQUENCE INVOLVING A SOLVENT ASSISTED CLAISEN-COPE REARRANGEMENT.

Author
FUJITA Y; ONISHI T; NISHIDA T
KURARAY CO. LTD., SAKAZU KURASHIKI OKAYAMA, JPN
Source
SYNTHESIS; DEU; DA. 1978; NO 8; PP. 612-614; BIBL. 6 REF.
Document type
Article
Language
English
Keyword (fr)
REACTION CHIMIQUE REACTIF GRIGNARD PYROLYSE ENONE TRANSPOSITION COPE PREPARATION COMPOSE ALIPHATIQUE COMPOSE ETHYLENIQUE COMPOSE BENZENIQUE HETEROCYCLE SOUFRE HETEROCYCLE OXYGENE CYCLE 5 CHAINONS TOLUENE(ALPHA -CHLORO)!ENT PENTENE-3ONE-2(METHYL-4)!ENT PENTENE-4ONE-2(BENZYL-3 METHYL-4)!FIN!ENT HEXADIENE-1,5OL-3(BENZYL-4 DIMETHYL-3,5)!FIN!ENT OCTENE-6ONE-2(METHYL-6 PHENYL-8)!FIN THIOPHENE(CHLOROMETHYL-2)!ENT THIOPHENE((METHYL-3P OXO-7P OCTENE-2P YL)-2)!FIN FURANNE(CHLOROMETHYL-2)!ENT FURANNE((METHYL-3P OXO-7P OCTENE-2P YL)-2)!FIN OCTENE-6ONE-2(ARYL-8 METHYL-6)!FIN MAGNESIUM(VINYL) BROMURE!ENT PYRROLIDONE-2(METHYL-1)!SUB CHIMIE ORGANIQUE
Keyword (en)
CHEMICAL REACTION GRIGNARD REAGENT PYROLYSIS ENONE COPE REARRANGEMENT PREPARATION ALIPHATIC COMPOUND ETHYLENIC COMPOUND BENZENIC COMPOUND SULFUR HETEROCYCLE OXYGEN HETEROCYCLE FIVE MEMBERED RING ORGANIC CHEMISTRY
Keyword (es)
QUIMICA ORGANICA
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry

Discipline
General chemistry and physical chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
PASCAL7960051116

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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