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A DIRECTING EFFECT OF NEIGHBORING AROMATIC GROUPS ON THE REGIOCHEMISTRY OF FORMATION AND ON THE STEREOCHEMISTRY OF ALKYLATION AND BROMINATION OF KETONE LITHIUM ENOLATES. EVIDENCE FOR LITHIUM-ARENE PI COORDINATION AND FOR A DRAMATIC EFFECT OF EVEN SMALL AMOUNTS OF COPPER(I) IN CONTROLLING STEREOCHEMISTRY AND IN LIMITING POLYALKYLATION

Author
POSNER GH; LENTZ CM
JOHNS HOPKINS UNIV. DEP. CHEM., BALTIMORE MD 21218, USA
Source
J. AMER. CHEM. SOC.; USA; DA. 1979; VOL. 101; NO 4; PP. 934-946; BIBL. 66 REF.
Document type
Article
Language
English
Keyword (fr)
EFFET GROUPE VOISIN ENOLISATION METHYLATION SILICIUM COMPOSE ORGANIQUE BROMATION COMPOSE MONOCYCLIQUE COMPOSE ETHYLENIQUE ENONE ENOL ETHER CETONE CUIVRE I CYANURE!ACT COMPOSE ALIPHATIQUE CYCLOPENTANONE(METHYL-3 PHENYL-3)!ENT CYCLOPENTENE(METHYL-3 PHENYL-3 TRIMETHYLSILOXY-1)!ENT CYCLOPENTENE-2ONE(PHENYL-3)!ENT CYCLOPENTANONE(DIMETHYL-2,3 PHENYL-3)!FIN CYCLOPENTENE(PHENYL-3 TRIMETHYLSILOXY-1)!ENT CYCLOPENTANONE(ALLYL-2 PHENYL-3)!FIN CYCLOPENTANONE(BROMO-2 METHYL-3 PHENYL-3)!FIN HEXANONE-3(P-TOLYL-5)!ENT CYCLOHEXANONE(BENZYL-3 METHYL-3)!ENT CYCLOHEXANONE(BUTYL-3 METHYL-3)!ENT CYCLOPENTANEACETIQUE ACIDE(METHYL-1 OXO-2 PHENYL-5) ESTER METHYLE!FIN ACETIQUE ACIDE(BROMO) ESTER METHYLE!ENT CUIVRE-LITHIUM(DIPHENYL)!ENT SILANE(CHLORO TRIMETHYL)!ENT LITHIUM AMIDURE(DIISOPROPYL)!ENT THF!SUB CHIMIE ORGANIQUE
Keyword (en)
NEIGHBOURING GROUP EFFECT ENOLIZATION METHYLATION BROMINATION MONOCYCLIC COMPOUND ETHYLENIC COMPOUND ENONE ENOL ETHER KETONE ALIPHATIC COMPOUND ORGANIC CHEMISTRY
Keyword (es)
QUIMICA ORGANICA
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry

Discipline
General chemistry and physical chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
PASCAL7960285036

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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