ROLE OF THROUGH SPACE 2P-3D OVERLAP IN THE ALKYLATION OF (OMEGA -N,N-DIMETHYLAMINOALKYL) DIPHENYLPHOSPHINES AND IN THE ALKALINE DECOMPOSITION OF RELATED QUATERNARY PHOSPHONIUM SALTS
- Author
- MCEWEN WE; SMITH JH; WOO EJ
UNIV. MASSACHUSETTS, DEP. CHEM.,AMHERST MA 01003,USA - Source
- J. AMER. CHEM. SOC.; USA; DA. 1980; VOL. 102; NO 8; PP. 2746-2751; BIBL. 31 REF.
- Document type
- Article
- Language
- English
- Keyword (fr)
- REACTION CHIMIQUE BENZENE!SUB METHANOL!SUB QUATERNARISATION ETAT TRANSITION DECOMPOSITION REACTION BASIQUE SOLUTION AQUEUSE PHOSPHORE COMPOSE ORGANIQUE PHOSPHONIUM QUATERNAIRE COMPOSE ORBITALE MOLECULAIRE EFFET SUBSTITUANT ALKYLATION PHOSPHINE TERTIAIRE PHOSPHINE(OMEGA -DIMETHYLAMINOALKYL DIPHENYL)!ENT TOLUENE(ALPHA -CHLORO)!ENT PHOSPHONIUM(BENZYL TRIPHENYL)!ENT PHOSPHONIUM(BENZYL OMEGA -DIMETHYLAMINOALKYL DIPHENYL) BROMURE!ENT PHOSPHONIUM(BENZYL DIPHENYL PROPYL) IODURE!ENT DMSO!SUB DIOXANNE CHIMIE ORGANIQUE
- Keyword (en)
- CHEMICAL REACTION QUATERNIZATION TRANSITION STATE DECOMPOSITION BASE REACTION AQUEOUS SOLUTIONS QUATERNARY PHOSPHONIUM COMPOUND MOLECULAR ORBITAL SUBSTITUENT EFFECT ALKYLATION TERTIARY PHOSPHINE DIOXANE ORGANIC CHEMISTRY
- Keyword (es)
- QUIMICA ORGANICA
- Classification
- Discipline
- General chemistry and physical chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- PASCAL8060320753
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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