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FORMATION OF A CARBINOLAMINE INTERMEDIATE IN THE TERTIARY AMINE CATALYZED ENOLIZATION OF OXALOACETIC ACID. AN ALTERNATIVE MECHANISM FOR ENOLIZATION

Author
YURKANIS BRUICE P
UNIV. CALIFORNIA, DEP. CHEMISTRY/SANTA BARBARA CA 93106/USA
Source
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY; ISSN 0002-7863; USA; DA. 1983; VOL. 105; NO 15; PP. 4982-4996; BIBL. 23 REF.
Document type
Article
Language
English
Keyword (fr)
ENOLISATION TAUTOMERIE CETOENOLIQUE SOLUTION AQUEUSE CATALYSE BASIQUE GENERALE AMINE TERTIAIRE EFFET MILIEU PH INTERMEDIAIRE REACTION HEMIAMINAL SOLUTION TAMPON COMPOSE ALIPHATIQUE CETOACIDE DIACIDE CARBOXYLIQUE OXALACETIQUE ACIDE CHIMIE ORGANIQUE
Keyword (en)
ENOLIZATION KETO ENOL TAUTOMERISM AQUEOUS SOLUTION GENERAL BASE CATALYSIS TERTIARY AMINE MEDIUM EFFECT PH REACTION INTERMEDIATE HEMIAMINAL BUFFER SOLUTION ALIPHATIC COMPOUND KETOACID DICARBOXYLIC ACID ORGANIC CHEMISTRY
Keyword (es)
QUIMICA ORGANICA
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
PASCAL83X0437096

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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