Quantum mechanical predictions of the stereoselectivities of proline-catalyzed asymmetric intermolecular aldol reactions
- Auteur
- BAHMANYAR, S1 ; HOUK, K. N1 ; MARTIN, Harry J2 ; LIST, Benjamin2
[1] Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, United States
[2] Department of Molecular Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, United States - Source
Journal of the American Chemical Society. 2003, Vol 125, Num 9, pp 2475-2479, 5 p ; ref : 25 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Domaine scientifique
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Editeur
- American Chemical Society, Washington, DC
- Pays de publication
- United States
- Type de document
- Article
- Langue
- English
- Mot clé (fr)
- Activité catalytique Aldolisation Benzaldéhyde dérivé Catalyse homogène Composé benzénique Composé monocyclique Etat transition Etude théorique Liaison hydrogène intramoléculaire Modèle thermodynamique Méthode fonctionnelle densité Proline Réaction asymétrique Réaction catalytique Schéma réactionnel Structure moléculaire Stéréosélectivité Sélectivité catalyseur α-Aminoacide Cyclohexanone dérivé
- Mot clé (en)
- Catalyst activity Aldol condensation Benzaldehyde derivatives Homogeneous catalysis Benzenic compound Monocyclic compound Transition state Theoretical study Intramolecular hydrogen bond Thermodynamic model Density functional method Proline Asymmetric reaction Catalytic reaction Reaction path Molecular structure Stereoselectivity Catalyst selectivity α-Aminoacid
- Mot clé (es)
- Actividad catalítica Aldolización Benzaldehído derivado Catálisis homogénea Compuesto bencénico Compuesto monocíclico Estado transitorio Estudio teórico Enlace hidrógeno intramolecular Modelo termodinámico Prolina Reacción asimétrica Reacción catalítica Esquema reacciones Estructura molecular Estereoselectividad Selectividad catalizador α-Aminoácido
- Classification
- Pascal
- 001 Sciences exactes et technologie / 001C Chimie / 001C03 Chimie organique / 001C03B Réactivité et mécanismes / 001C03B02 Cinétique et mécanisme des réactions
- Discipline
- Organic chemistry
- Provenance
- Inist-CNRS
- Base de données
- PASCAL
- Identifiant INIST
- 14591787
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja028812d 
https://dx.doi.org/10.1021/ja028812d
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